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A new sodium- and manganese-based trivanadate NaMn2V3O10: synthesis, structural and magnetic insights

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Abstract

Single crystals of the new compound, NaMn2V3O10, were grown by conventional solid-state reaction. The crystal structure of the synthesized sample was determined using single-crystal X-ray diffraction data. NaMn2V3O10 crystallizes in the triclinic system with space group P\(\stackrel{-}{1}\) and cell parameters a = 6.854 (2) Å, b = 6.877 (2) Å, c = 9.716 (2) Å, α = 100.604 (1)°, β = 104.169 (1)°, and γ = 101.390 (1)°. The structure of this vanadate built up from the connection of V3O10 groups and MnO6 octahedra via corners leading to an open three-dimensional framework delimiting tunnels along [001] direction, where the Na+ cations are localized. The powder of NaMn2V3O10 was prepared by Pechini method. The magnetic measurement has been evidenced by Curie–Weiss behavior above 4.5 K with θ = − 25.46 K demonstrating the occurrence of predominant antiferromagnetic interactions between Mn2+ cations.

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Authors and Affiliations

  1. Laboratoire de Chimie Appliquée des Matériaux, Centre des Sciences des Matériaux, Faculty of Science, Mohammed V University in Rabat, Avenue Ibn Battouta, BP 1014, Rabat, Morocco

    Elhassan Benhsina, Abderrazzak Assani, Mohamed Saadi & Lahcen El Ammari

  2. Laboratory of Physics of Condensed Matter, University of Picardie Jules Verne, Scientific Pole, 33 Rue Saint-Leu, 80039, Amiens Cedex 1, France

    Abdelilah Lahmar

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  1. Elhassan Benhsina
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  2. Abderrazzak Assani
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  3. Mohamed Saadi
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  4. Abdelilah Lahmar
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  5. Lahcen El Ammari
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Correspondence to Elhassan Benhsina.

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Benhsina, E., Assani, A., Saadi, M. et al. A new sodium- and manganese-based trivanadate NaMn2V3O10: synthesis, structural and magnetic insights. Monatsh Chem 151, 677–684 (2020). https://doi.org/10.1007/s00706-020-02608-3

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  • DOI: https://doi.org/10.1007/s00706-020-02608-3

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