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A novel electrochemical method for the preparation of Pt/C nanostructured materials

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Abstract

An original method for the preparation of Pt/C materials dispersed by means of platinum electrodeposition on the carbon particles which are in the form of suspension has been proposed. The materials were studied by XRD, cyclic voltammetry, SEM and TEM electron microscopy. The obtained Pt/C materials contain from 9 to 14 wt% Pt. The average size of platinum particles is from 7 to 15 nm; electrochemically active surface area of Pt/C is from 15 to 29 m2 g−1 (Pt). The resulting materials exhibit catalytic activity in the oxygen electroreduction reaction which predominantly flows through the 4-electron mechanism.

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Acknowledgements

This work was supported by the Ministry of Education and Science RF (Grant 13.3005.2017/4.6). The authors thank the Department of Structural Studies in the Institute of Organic Chemistry of the Russian Academy of Sciences for providing the study of samples by the scanning electron microscopy.

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Authors and Affiliations

  1. Chemistry Faculty, Southern Federal University, 7 Zorge St., Rostov-on-Don, Russia

    Ivan N. Novomlinskiy, Olga I. Safronenko & Vladimir E. Guterman

  2. National University of Science and Technology «MISIS», 4 Leninskiy Ave., Moscow, Russia

    Natalija Yu. Tabachkova

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  1. Ivan N. Novomlinskiy
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  2. Natalija Yu. Tabachkova
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  3. Olga I. Safronenko
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  4. Vladimir E. Guterman
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Correspondence to Ivan N. Novomlinskiy.

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Novomlinskiy, I.N., Tabachkova, N.Y., Safronenko, O.I. et al. A novel electrochemical method for the preparation of Pt/C nanostructured materials. Monatsh Chem 150, 631–637 (2019). https://doi.org/10.1007/s00706-019-2383-3

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  • DOI: https://doi.org/10.1007/s00706-019-2383-3

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