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Applicability of voltammetric determination of diclofenac at carbon paste electrodes to the analysis of aqueous solutions purified by adsorption and/or ionic liquid-based ion exchange

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Abstract

This contribution summarises the results from an initial electrochemical study of anti-inflammatory drug diclofenac at carbon paste electrodes focused on the applicability to the determination of this substance in environmental samples, namely, in aqueous solutions containing diclofenac. The substance of interest could be readily oxidized at carbon paste electrodes modified in situ with cetyltrimethylammonium bromide enhancing the response of diclofenac. The respective voltammetric method has been characterised with respect to the linear range, detection capabilities, and the overall analytical performance. Applicability of the procedure developed was examined on a set of model samples polluted with diclofenac before and after treatment with charcoal and/or various lipophilic ionic liquids to define the efficiency of such purification process.

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Acknowledgements

We are grateful to thank for support by Technology Agency of the Czech Republic, Project No. TH02030200. In addition, authors would like to thank Dr. Tomáš Mikysek, their colleague from the Department of Analytical Chemistry, for some valuable comments concerning the interpretation of the electrode oxidation of diclofenac.

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Authors and Affiliations

  1. Chemical Technology Group, Faculty of Chemical Technology, Institute of Environmental and Chemical Engineering, University of Pardubice, Studentska 573, 532 10, Pardubice, Czech Republic

    Barbora Kamenická & Tomáš Weidlich

  2. Department of Analytical Chemistry, Faculty of Chemical Technology, University of Pardubice, Studentska 573, 532 10, Pardubice, Czech Republic

    Andrea Bartášková & Ivan Švancara

Authors
  1. Barbora Kamenická
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  2. Andrea Bartášková
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  3. Ivan Švancara
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  4. Tomáš Weidlich
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Correspondence to Ivan Švancara or Tomáš Weidlich.

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Kamenická, B., Bartášková, A., Švancara, I. et al. Applicability of voltammetric determination of diclofenac at carbon paste electrodes to the analysis of aqueous solutions purified by adsorption and/or ionic liquid-based ion exchange. Monatsh Chem 150, 429–437 (2019). https://doi.org/10.1007/s00706-019-2354-8

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  • DOI: https://doi.org/10.1007/s00706-019-2354-8

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