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A green eco approach toward the synthesis of novel 4-iminoquinoline derivatives using Brønsted acid nanocatalysts

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Abstract

A series of novel 4-iminoquinolines were synthesized from the reaction of 2-aminobenzonitrile, orthoesters, and active methylenes in the presence of Brønsted acid nanocatalysts (Fe3O4@APTES-MAH NPs or VSA NRs) under solvent-free conditions. VSA NRs were prepared by the reaction of the chlorosulfonic acid and sodium monovanadate at high purity. The amine-surfaced Fe3O4@APTES NPs prepared using the coating of Fe3O4 nanoparticles with 3-aminopropyltriethoxysilane were further modified with maleic anhydride to produce Fe3O4@APTES-MAH NPs. The reaction is characterized by high yields, simple purification of the products, inexpensive, short reaction times, reusability, and stability of the catalysts.

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Acknowledgements

We are grateful to the Yasouj University for supporting this work.

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Authors and Affiliations

  1. Department of Chemistry, Yasouj University, Yasouj, 75918-74831, Iran

    Elham Kanaani & Masoud Nasr-Esfahani

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  1. Elham Kanaani
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  2. Masoud Nasr-Esfahani
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Correspondence to Masoud Nasr-Esfahani.

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Kanaani, E., Nasr-Esfahani, M. A green eco approach toward the synthesis of novel 4-iminoquinoline derivatives using Brønsted acid nanocatalysts. Monatsh Chem 149, 543–550 (2018). https://doi.org/10.1007/s00706-017-2069-7

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  • DOI: https://doi.org/10.1007/s00706-017-2069-7

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