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Isocyanide-based multicomponent reaction for the formation of 1,3-oxathiolane-2-imine derivatives

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Abstract

The adduct of isocyanide and elemental sulfur has been employed as the isothiocyanate source in reaction with oxirane to form 1,3-oxathiolane-2-imine derivatives. The optimum conditions are developed using HMPA at 55 °C for 12 h. Various isocyanides and oxiranes were tolerated under the optimum conditions.

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Authors and Affiliations

  1. Chemistry Department, Faculty of Science, University of Zabol, Zabol, Iran

    Alireza Samzadeh-Kermani & Samira Zamenraz

Authors
  1. Alireza Samzadeh-Kermani
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  2. Samira Zamenraz
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Correspondence to Alireza Samzadeh-Kermani.

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Samzadeh-Kermani, A., Zamenraz, S. Isocyanide-based multicomponent reaction for the formation of 1,3-oxathiolane-2-imine derivatives. Monatsh Chem 148, 1753–1760 (2017). https://doi.org/10.1007/s00706-017-1939-3

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  • DOI: https://doi.org/10.1007/s00706-017-1939-3

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