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Voltammetric determination of sodium anthraquinone-2-sulfonate using silver solid amalgam electrodes

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Abstract

Voltammetric determination of sodium anthraquinone-2-sulfonate (AQ) was investigated at a polished silver solid amalgam electrode (p-AgSAE) and at a mercury meniscus modified silver solid amalgam electrode (m-AgSAE) (inner diameter of both 0.5 mm). The reaction mechanisms of AQ at p-AgSAE and at m-AgSAE were studied by cyclic voltammetry, direct current voltammetry, and by elimination voltammetry with linear scan. Limits of detection obtained by differential pulse voltammetry were 1 × 10−6 mol dm−3 for p-AgSAE and 4 × 10−7 mol dm−3 for m-AgSAE. Both electrodes were successfully applied for differential pulse voltammetry of AQ in model samples of deionized water, river water, and human urine.

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Acknowledgements

This research was carried out within the framework of the Specific University Research Charles University (SVV). TN and ŠS are grateful for the financial support from J. Heyrovský Institute of Physical Chemistry of the CAS, v.v.i., JB and VV would like to thank the Grant Agency of the Czech Republic (Project P206/12/G151).

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Authors and Affiliations

  1. J. Heyrovský Institute of Physical Chemistry of the CAS, v.v.i., Dolejškova 3, 182 23, Prague 8, Czech Republic

    Štěpánka Skalová & Tomáš Navrátil

  2. Charles University, Faculty of Science, Department of Analytical Chemistry, UNESCO Laboratory of Environmental Electrochemistry, Hlavova 2030/8, 128 43, Prague 2, Czech Republic

    Štěpánka Skalová, Jiří Barek & Vlastimil Vyskočil

Authors
  1. Štěpánka Skalová
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  2. Tomáš Navrátil
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  3. Jiří Barek
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  4. Vlastimil Vyskočil
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Correspondence to Tomáš Navrátil.

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Skalová, Š., Navrátil, T., Barek, J. et al. Voltammetric determination of sodium anthraquinone-2-sulfonate using silver solid amalgam electrodes. Monatsh Chem 148, 577–583 (2017). https://doi.org/10.1007/s00706-017-1926-8

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  • DOI: https://doi.org/10.1007/s00706-017-1926-8

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