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Synthesis of bis-ferrocenylpyrazoles via ferrocenylalkylation reaction

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Abstract

Regioselective synthesis of bis-ferrocenylpyrazole derivatives in biphasic aquatic–organic system under catalysis with HBF4 was carried out. The regioselectivity of these reactions depending on the electronic effects of substituents in pyrazole moiety was studied.

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Acknowledgements

The reported study was funded by the Russian Foundation for Basic Research (RFBR), according to the research project No. 16-33-60163 (mol_a_dk).

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Authors and Affiliations

  1. A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation

    Alexey N. Rodionov, Maria D. Gerasimova, Elena Yu. Osipova, Alexander A. Korlyukov, Alexander S. Peregudov & Alexander A. Simenel

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  1. Alexey N. Rodionov
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  2. Maria D. Gerasimova
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  3. Elena Yu. Osipova
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  4. Alexander A. Korlyukov
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  5. Alexander S. Peregudov
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  6. Alexander A. Simenel
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Correspondence to Elena Yu. Osipova.

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Rodionov, A.N., Gerasimova, M.D., Osipova, E.Y. et al. Synthesis of bis-ferrocenylpyrazoles via ferrocenylalkylation reaction. Monatsh Chem 148, 925–932 (2017). https://doi.org/10.1007/s00706-016-1895-3

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  • DOI: https://doi.org/10.1007/s00706-016-1895-3

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