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A new look at NaBrF4: the most BrF3-rich tetrafluoridobromate(III) by mass

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Abstract

Sodium tetrafluoridobromate(III) was synthesized and characterized. The compound crystallizes isotypic to potassium and rubidium tetrafluoridobromate(III) in the tetragonal space group type I4/mcm with a = 5.7239(8) Å, c = 10.331(2) Å, V = 338.47(12) Å3, and Z = 4 at T = 110 K. Also, the compound was investigated by means of powder X-ray diffraction, IR and Raman spectroscopy, and theoretical calculations.

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Acknowledgments

We thank Deutsche Forschungsgemeinschaft for funding. F.K. thanks the DFG for a Heisenberg-professorship. We thank Solvay for generous donations of fluorine.

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Authors and Affiliations

  1. Fachbereich Chemie, Philipps-Universität Marburg, Marburg, Germany

    Sergei I. Ivlev & Florian Kraus

  2. Institute of Applied Physics and Technology, Tomsk Polytechnic University, Tomsk, Russia

    Roman V. Ostvald

Authors
  1. Sergei I. Ivlev
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  2. Roman V. Ostvald
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  3. Florian Kraus
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Correspondence to Florian Kraus.

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Ivlev, S.I., Ostvald, R.V. & Kraus, F. A new look at NaBrF4: the most BrF3-rich tetrafluoridobromate(III) by mass. Monatsh Chem 147, 1661–1668 (2016). https://doi.org/10.1007/s00706-016-1799-2

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