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Catalytic activity of metal-doped porous materials in the salicylaldehyde Petasis-Borono Mannich reaction

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Abstract

The necessity of a catalyst in the Petasis-Borono Mannich multicomponent reaction was studied. Besides the catalyst-free reaction, monometallic and bimetallic catalysts were tested on different supports with various metal loadings. It was concluded that a 4 Å molecular sieve-supported copper catalyst with low (1.2 wt%) copper content accelerated the coupling the most.

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Acknowledgments

Anna Fodor is grateful to the fellowship of the Pro Progressio foundation.

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Authors and Affiliations

  1. Department of Organic Chemistry and Technology, Budapest University of Technology and Economics, Műegyetem rkp. 3, 1111, Budapest, Hungary

    Anna Fodor & Zoltán Hell

  2. Institute of Chemistry of Poitiers: Materials and Natural Resources (IC2MP) UMR-CNRS 7285, University of Poitiers, 4, Rue Michel Brunet (Bât B27), 86073, Poitiers Cedex, France

    Anna Fodor & Laurence Pirault-Roy

Authors
  1. Anna Fodor
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  2. Zoltán Hell
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  3. Laurence Pirault-Roy
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Correspondence to Zoltán Hell.

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Fodor, A., Hell, Z. & Pirault-Roy, L. Catalytic activity of metal-doped porous materials in the salicylaldehyde Petasis-Borono Mannich reaction. Monatsh Chem 147, 749–753 (2016). https://doi.org/10.1007/s00706-016-1681-2

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  • DOI: https://doi.org/10.1007/s00706-016-1681-2

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