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Symmetrical disulfide synthesis via nickel-catalysis using potassium sulfide as sulfur source

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Abstract

An efficient one-pot method for the synthesis of organic disulfides from aryl and alkyl halides and potassium sulfide has been described. K2S acts as an inexpensive and readily available sulfur source. A variety of symmetric diaryl and dialkyl disulfides was prepared in good to excellent yields using NiCl2·6H2O and acetylacetone as the catalytic system.

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Acknowledgments

Financial support from Ilam university research council is gratefully acknowledged.

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Authors and Affiliations

  1. Department of Chemistry, Basic of Sciences Faculty, Ilam University, Ilam, Iran

    Mohammad Soleiman-Beigi & Zeinab Arzehgar

Authors
  1. Mohammad Soleiman-Beigi
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  2. Zeinab Arzehgar
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Correspondence to Mohammad Soleiman-Beigi.

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Soleiman-Beigi, M., Arzehgar, Z. Symmetrical disulfide synthesis via nickel-catalysis using potassium sulfide as sulfur source. Monatsh Chem 147, 1759–1763 (2016). https://doi.org/10.1007/s00706-016-1673-2

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  • DOI: https://doi.org/10.1007/s00706-016-1673-2

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