Monatshefte für Chemie - Chemical Monthly

, Volume 147, Issue 2, pp 341–348

Monomeric aminoalcoholates of aluminium(III), gallium(III), and indium(III)

Original Paper

DOI: 10.1007/s00706-015-1626-1

Cite this article as:
Biegger, F. & Barth, S. Monatsh Chem (2016) 147: 341. doi:10.1007/s00706-015-1626-1

Abstract

The synthesis of novel, homoleptic group 13 alkoxides is presented. M(OCH(CH2NR2)2)3, where M=Al, Ga, In and R=Me, Et, are characterised by room temperature NMR spectroscopy and single-crystal XRD showing the monomeric nature of all aminoalcoholates.

Graphical abstract

Keywords

Aluminium alkoxides Gallium alkoxides Indium alkoxides Aminoalcohols Coordination chemistry 

Supplementary material

706_2015_1626_MOESM1_ESM.cif (2.2 mb)
Supplementary material 1 (CIF 2267 kb)
706_2015_1626_MOESM2_ESM.cif (425 kb)
Supplementary material 2 (CIF 424 kb)
706_2015_1626_MOESM3_ESM.cif (708 kb)
Supplementary material 3 (CIF 708 kb)
706_2015_1626_MOESM4_ESM.cif (25 kb)
Supplementary material 4 (CIF 25 kb)
706_2015_1626_MOESM5_ESM.cif (953 kb)
Supplementary material 5 (CIF 953 kb)

Copyright information

© Springer-Verlag Wien 2015

Authors and Affiliations

  1. 1.Institute of Materials ChemistryVienna University of TechnologyViennaAustria

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