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Monomeric aminoalcoholates of aluminium(III), gallium(III), and indium(III)

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Abstract

The synthesis of novel, homoleptic group 13 alkoxides is presented. M(OCH(CH2NR2)2)3, where M=Al, Ga, In and R=Me, Et, are characterised by room temperature NMR spectroscopy and single-crystal XRD showing the monomeric nature of all aminoalcoholates.

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Acknowledgments

We thank M. Czakler for some support with single-crystal XRD measurements, B. Stöger for help with twin refinement, and the X-ray Centre for access to the diffractometer.

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Authors and Affiliations

  1. Institute of Materials Chemistry, Vienna University of Technology, Getreidemarkt 9/BC/02, Vienna, Austria

    Felix Biegger & Sven Barth

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  1. Felix Biegger
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  2. Sven Barth
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Correspondence to Sven Barth.

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Biegger, F., Barth, S. Monomeric aminoalcoholates of aluminium(III), gallium(III), and indium(III). Monatsh Chem 147, 341–348 (2016). https://doi.org/10.1007/s00706-015-1626-1

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  • DOI: https://doi.org/10.1007/s00706-015-1626-1

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