Monatshefte für Chemie - Chemical Monthly

, Volume 147, Issue 2, pp 341–348 | Cite as

Monomeric aminoalcoholates of aluminium(III), gallium(III), and indium(III)

  • Felix Biegger
  • Sven Barth
Original Paper


The synthesis of novel, homoleptic group 13 alkoxides is presented. M(OCH(CH2NR2)2)3, where M=Al, Ga, In and R=Me, Et, are characterised by room temperature NMR spectroscopy and single-crystal XRD showing the monomeric nature of all aminoalcoholates.

Graphical abstract


Aluminium alkoxides Gallium alkoxides Indium alkoxides Aminoalcohols Coordination chemistry 



We thank M. Czakler for some support with single-crystal XRD measurements, B. Stöger for help with twin refinement, and the X-ray Centre for access to the diffractometer.

Supplementary material

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Supplementary material 1 (CIF 2267 kb)
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Supplementary material 2 (CIF 424 kb)
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Supplementary material 3 (CIF 708 kb)
706_2015_1626_MOESM4_ESM.cif (25 kb)
Supplementary material 4 (CIF 25 kb)
706_2015_1626_MOESM5_ESM.cif (953 kb)
Supplementary material 5 (CIF 953 kb)


  1. 1.
    Valet M, Hoffman DM (2001) Chem Mater 13:2135CrossRefGoogle Scholar
  2. 2.
    Mathur S, Barth S, Werner U, Hernandez-Ramirez F, Romano-Rodriguez A (2008) Adv Mater 20:1550CrossRefGoogle Scholar
  3. 3.
    Barth S, Seifner MS, Bernardi J (2014) J Mater Chem C 2:5747CrossRefGoogle Scholar
  4. 4.
    Mathur S, Barth S, Shen H (2005) Chem Vap Depos 11:11CrossRefGoogle Scholar
  5. 5.
    Sharma N, Sharma V, Nagar M, Bohra R, Kaushik A, Mathur S, Barth S (2008) J Coord Chem 61:2234CrossRefGoogle Scholar
  6. 6.
    Lichtenberger R, Schubert U (2010) J Mater Chem 20:9287CrossRefGoogle Scholar
  7. 7.
    Bradley DC, Mehrotra RC, Rothwel IP, Singh A (2001) Alkoxo and aryloxo derivatives of metals, 2nd edn. Academic Press Inc, LondonGoogle Scholar
  8. 8.
    Herrmann WA, Huber NW, Runte O (1995) Angew Chem Int Ed 34:2187CrossRefGoogle Scholar
  9. 9.
    Daniele S, Tcheboukov D, Hubert-Pfalzgraf LG, Lecocq S (2002) Inorg Chem Commun 5:347CrossRefGoogle Scholar
  10. 10.
    Herrmann WA, Huber NW, Priermeier T (1994) Angew Chem 106:102CrossRefGoogle Scholar
  11. 11.
    Barth S, Biegger F, Puchberger M (2015) Dalton Trans 44:16439CrossRefGoogle Scholar
  12. 12.
    Carmalt CJ, King SJ (2006) Coord Chem Rev 250:682CrossRefGoogle Scholar
  13. 13.
    Saegusa T, Ueshima T (1967) Inorg Chem 6:1679CrossRefGoogle Scholar
  14. 14.
    Miinea LA, Suh S, Hoffman DM (1999) Inorg Chem 38:4447CrossRefGoogle Scholar
  15. 15.
    Kraft A, Beck J, Krossing I (2011) Chem Eur J 17:12975CrossRefGoogle Scholar
  16. 16.
    Raabe I, Wagner K, Guttsche K, Wang M, Grätzel M, Santiso-Quiñones G, Krossing I (2009) Chem Eur J 15:1966CrossRefGoogle Scholar
  17. 17.
    Wang Y, Zhang W, Li Y, Ye L, Yang G (1999) Chem Mater 11:530CrossRefGoogle Scholar
  18. 18.
    Li H, Zhang F, Wang Y, Zheng D (2003) Mater Sci Eng, B 100:40CrossRefGoogle Scholar
  19. 19.
    Sun HS, Zhao Q, Liu YJ, Hu HM, You XZ, Zhou ZY (1999) J Coord Chem 47:459CrossRefGoogle Scholar
  20. 20.
    Basharat S, Carmalt CJ, Barnett SA, Tocher DA, Davies HO (2007) Inorg Chem 46:9473CrossRefGoogle Scholar
  21. 21.
    Basharat S, Carmalt CJ, Palgrave R, Barnett SA, Tocher DA, Davies HO (2008) J Organomet Chem 693:1787CrossRefGoogle Scholar
  22. 22.
    Becker R, Weiß J, Winter M, Merz K, Fischer RA (2001) J Organomet Chem 630:253CrossRefGoogle Scholar
  23. 23.
    Campbell KN, LaForge RA, Campbell BK (1949) J Org Chem 14:346CrossRefGoogle Scholar
  24. 24.
    Lichtenberger R, Puchberger M, Baumann SO, Schubert U (2009) J Sol-Gel Sci Technol 50:130CrossRefGoogle Scholar
  25. 25.
    Bains MS (1962) Can J Chem-Rev Can Chim 40:381CrossRefGoogle Scholar
  26. 26.
    Basharat S, Carmalt CJ, King SJ, Peters ES, Tocher DA (2004) Dalton Trans 21:3475 CrossRefGoogle Scholar
  27. 27.
    Basharat S, Knapp CE, Carmalt CJ, Barnett SA, Tocher DA (2008) New J Chem 32:1513CrossRefGoogle Scholar
  28. 28.
    Pugh D, Bloor LG, Parkin IP, Carmalt CJ (2012) Chem Eur J 18:6079CrossRefGoogle Scholar
  29. 29.
    Sheldrick GM (2015) Acta Cryst A 71:3CrossRefGoogle Scholar

Copyright information

© Springer-Verlag Wien 2015

Authors and Affiliations

  1. 1.Institute of Materials ChemistryVienna University of TechnologyViennaAustria

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