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Monatshefte für Chemie - Chemical Monthly

, Volume 147, Issue 2, pp 341–348 | Cite as

Monomeric aminoalcoholates of aluminium(III), gallium(III), and indium(III)

  • Felix Biegger
  • Sven Barth
Original Paper

Abstract

The synthesis of novel, homoleptic group 13 alkoxides is presented. M(OCH(CH2NR2)2)3, where M=Al, Ga, In and R=Me, Et, are characterised by room temperature NMR spectroscopy and single-crystal XRD showing the monomeric nature of all aminoalcoholates.

Graphical abstract

Keywords

Aluminium alkoxides Gallium alkoxides Indium alkoxides Aminoalcohols Coordination chemistry 

Notes

Acknowledgments

We thank M. Czakler for some support with single-crystal XRD measurements, B. Stöger for help with twin refinement, and the X-ray Centre for access to the diffractometer.

Supplementary material

706_2015_1626_MOESM1_ESM.cif (2.2 mb)
Supplementary material 1 (CIF 2267 kb)
706_2015_1626_MOESM2_ESM.cif (425 kb)
Supplementary material 2 (CIF 424 kb)
706_2015_1626_MOESM3_ESM.cif (708 kb)
Supplementary material 3 (CIF 708 kb)
706_2015_1626_MOESM4_ESM.cif (25 kb)
Supplementary material 4 (CIF 25 kb)
706_2015_1626_MOESM5_ESM.cif (953 kb)
Supplementary material 5 (CIF 953 kb)

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Copyright information

© Springer-Verlag Wien 2015

Authors and Affiliations

  1. 1.Institute of Materials ChemistryVienna University of TechnologyViennaAustria

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