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Formation and investigation of 6-cysteinyl amino methylated β-cyclodextrin self-assembled monolayers

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Abstract

6 -Cysteinyl amino methylated β-cyclodextrin was adsorbed on Au(111) as well as on mercury electrode. Scanning probe microscopy and electrochemical techniques confirmed that a chemisorbed self-assembled monolayer (SAM) of the β-cyclodextrin is formed, proving that a single –SH moiety located in the cysteinyl group is sufficient to anchor the entire methylated β-cyclodextrin molecule to the electrode surface. Thus, formed SAM can potentially serve as sensor layer for various organic molecules such as pesticides, antibiotics, and optically active compounds.

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Acknowledgments

VK thanks for the financial support from Sciex (10.209) as well as Academy of Sciences of the Czech Republic (L200401501). Grant Agency of the Czech Republic is greatly acknowledged (14-05180S) by MH. Financial support from the French National Research Agency (ANR BLAN femtomotile) to CL and JMM is acknowledged.

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Authors and Affiliations

  1. J. Heyrovsky Institute of Physical Chemistry of the ASCR, v. v. i. Dolejškova 2155/3, 182 23, Prague 8, Czech Republic

    Viliam Kolivoška, Romana Sokolová, Jana Kocábová & Magdaléna Hromadová

  2. Département de Chimie, École Normale Supérieure, PSL Research University, 24, rue Lhomond, 75005, Paris, France

    Christina Loukou & Jean-Maurice Mallet

  3. Sorbonne Universités, UPMC Univ Paris 06, LBM, 4 place Jussieu, 75005, Paris, France

    Christina Loukou & Jean-Maurice Mallet

  4. CNRS, UMR 7203 LBM, 75005, Paris, France

    Christina Loukou & Jean-Maurice Mallet

  5. Faculty of Science, J. E. Purkyně University, České mládeže 8, 400 96, Ústí nad Labem, Czech Republic

    Magdaléna Hromadová

Authors
  1. Viliam Kolivoška
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  2. Romana Sokolová
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  3. Jana Kocábová
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  4. Christina Loukou
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  5. Jean-Maurice Mallet
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  6. Magdaléna Hromadová
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Correspondence to Viliam Kolivoška.

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Kolivoška, V., Sokolová, R., Kocábová, J. et al. Formation and investigation of 6-cysteinyl amino methylated β-cyclodextrin self-assembled monolayers. Monatsh Chem 147, 45–51 (2016). https://doi.org/10.1007/s00706-015-1609-2

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  • DOI: https://doi.org/10.1007/s00706-015-1609-2

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