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Synthesis and characterization of LiClO4·H2O

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Abstract

Lithium perchlorate monohydrate was synthesized and characterized. The compound crystallizes isotypic to sodium perchlorate monohydrate in the monoclinic space group type C2/c with a = 14.2592(6) Å, b = 5.2921(2) Å, c = 10.3382(4) Å, β = 111.765(2)°, V = 724.52(5) Å3, Z = 8, at T = 110 K. Additionally, we investigated the compound by means of IR and Raman spectroscopy, powder X-ray diffraction, thermal analysis (TG/DSC), and solid-state computational calculations.

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Acknowledgments

This work is financially supported by Tomsk Polytechnic University within the Program of Improving the Competitiveness. S. I., D. A., and N. E. thank the Science Department of Tomsk Polytechnic University for a mobility grant. F. K. and S. I. thank Uwe Justus for the measurements of TG/DSC, Dr. Istemi Kuzu for helping with the FIR and Raman devices, Dr. Uwe Linne for the consultations on the elemental analyses, and Dr. Klaus Harms at the X-ray Diffraction Facilities for the data acquisition of the single crystals. F. K. thanks the DFG for a Heisenberg professorship.

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Authors and Affiliations

  1. Department of Rare and Radioactive Element Technology, Institute of Physics and Technology, Tomsk Polytechnic University, 30 Lenina Avenue, Tomsk, 634050, Russia

    S. I. Ivlev, D. V. Akimov & N. B. Egorov

  2. Fachbereich Chemie, Philipps-Universität Marburg, Hans-Meerwein-Straße 4, 35032, Marburg, Germany

    S. I. Ivlev & F. Kraus

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  1. S. I. Ivlev
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  2. D. V. Akimov
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  3. N. B. Egorov
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  4. F. Kraus
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Correspondence to N. B. Egorov or F. Kraus.

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Ivlev, S.I., Akimov, D.V., Egorov, N.B. et al. Synthesis and characterization of LiClO4·H2O. Monatsh Chem 147, 279–288 (2016). https://doi.org/10.1007/s00706-015-1603-8

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  • DOI: https://doi.org/10.1007/s00706-015-1603-8

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