Abstract
The industrial paintshop wastewater from an automotive industry which contained nitrogen organic compounds was investigated in the study. Chemical oxygen demand (COD) values and degradation processes were measured and characterized by HPLC and GC–MS analysis. It was also observed by HPLC method that organic compounds with a high content of organic nitrogen were successfully degraded by the mixture of enzymes. The COD removal efficiency achieved in the case of unpretreated water was approximately 48 %. However, the COD removal efficiency increased up to 76 % when a mixture of enzymes was used for the wastewater pretreatment.
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Chan YJ, Chong MF, Law CL, Hassell DG (2009) Chem Eng J 155:1
Mohammed RR, Chong MF (2014) J Environ Manage 132:237
Karam J, Nicell JA (1997) J Chem Technol Biot 69:141
Loncar N, Bozic N, Lopez-Santin J, Vujcic Z (2013) Bioresour Technol 147:177
Mukherjee S, Basak B, Bhunia B, Dey A, Mondal B (2013) Rev Environ Sci Bio 12:61
Oller I, Malato S, Sanchez-Perez JA (2011) Sci Total Environ 409:4141
Prieto-Rodirguez L, Spasiano D, Oller I, Fernandez-Calderero I, Aguera A, Malato S (2013) Catal Today 209:188
Karimi S, Abdulkhani A, Ghazali AHB, Ahmadun FR, Karimi A (2009) Desalination 249:870
Hamza M, Khoufi S, Sayadi S (2012) Food Chem 131:1430
Garcia HA, Hoffman CM, Kinney KA, Lawler DF (2011) Water Res 45:1921
Jia JB, Zhang SP, Wang P, Wang HJ (2012) J Hazard Mater 205:150
Duran N, Esposito E (2000) Appl Catal B-Environ 28:83
Tortella G, Duran N, Rubilar O, Parada M, Diez MC (2015) Crit Rev Biotechnol 35:165
Alexandre VMF, Valente AM, Cammarota MC, Freire DMG (2011) Renew Energ 36:3439
Cammarota MC, Freire DMG (2006) Bioresour Technol 97:2195
Cammarota MC, Rosa DR, Duarte ICS, Saavedra NK, Varesche MBA, Zaiat M, Freire DMG (2013) Environ Technol 34:417
JdoN Silva, Gutarra MLE, Freire DMG, Cammarota MC (2013) J Bioprocess Biotech 3:139
Abdel-Raouf N, Al-Homaidan AA, Ibraheem IBM (2012) Saudi J Biol Sci 19:257
Gajski G, Orescanin V, Garaj-Vrhovac V (2012) Ecotox Environ Safe 78:253
Vedrenne M, Vasquez-Medrano R, Prato-Garcia D, Frontana-Uribe BA, Ibanez JG (2012) J Hazard Mater 205:208
Bidoia ED, de Sousa ML, Tamada IS, Matos Cruz J, de Angelis DdF (2013) Environ Manage Sustain Dev 2:106
Sangave PC, Pandit AB (2006) J Environ Manage 80:36
Špalková V, Lazor M, Smolinská M, Takáčová A, Hutňan M, Bodík I, Ryba J, Gál M, Žemlička L, Pangallo D, Mackuľak T (2016) Monatsh Chem. doi:10.1007/s00706-015-1572-y
Mackuľak T, Prousek J, Švorc Ľ (2011) Monatsh Chem 142:561
Acknowledgments
This work was supported by the scientific grant agency of the Ministry of Education of the Slovak Republic (ME SR) and of Slovak Academy of Sciences VEGA project No. 1/0589/12. This contribution is also the result of the project implementation Centre of Excellence of Integrated Flood Protection of Territory ITMS 26240120004 supported by the Research and Development Operational Program funded by the ERDF. TM acknowledge the financial support of the Slovak University of Technology in Bratislava (Grantová schéma na podporu excelentných tímov mladých výskumníkov v podmienkach STU v Bratislave: Výskyt liečiv, drog a rezistentných typov baktérií v odpadových vodách zo zdravotných zariadení na Slovensku a ich možné odstránenie pomocou progresívnych procesov).
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Mackuľak, T., Bodík, I., Smolinská, M. et al. Automotive industry wastewater treatment by mixture of enzymes. Monatsh Chem 147, 159–164 (2016). https://doi.org/10.1007/s00706-015-1579-4
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DOI: https://doi.org/10.1007/s00706-015-1579-4