Skip to main content
SpringerLink
Log in

Poly(4-vinylpyridine-co-ethylvinylbenzene) as heterogeneous reusable catalyst for the synthesis of benzoyl fumarate

  • Original Paper
  • Published:
Monatshefte für Chemie - Chemical Monthly Aims and scope Submit manuscript

Abstract

Poly(4-vinylpyridine-co-ethylvinylbenzene) 25 % cross-linked (with divinylbenzene) has been found to be an effective heterogeneous catalyst for the synthesis of benzoyl fumarate from aldehyde and dimethyl acetylenedicarboxylate. Various aromatic aldehydes undergo this reaction with good yield in presence of 15 wt% of the catalyst. The catalyst was recovered and reused six times without appreciable alteration in activity.

Graphical abstract

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1

Similar content being viewed by others

References

  1. Reymond S, Cossy J (2008) Chem Rev 108:5359

  2. Pindur U, Lutz G, Otto C (1993) Chem Rev 93:741

    Article  CAS  Google Scholar 

  3. Yamada K, Ino K, Takashashi S, Ohashi T, Watanabe K (1988) N2-(1-carboxy-3-oxo-3-phenyl)-L-lysine derivatives, their preparation, and their use as intermediates for potential antihypertensives. Eur Patent EP 239062, 30 Sep 1987; Chem Abstr 109:110904z

  4. Kagan HB, Riant O (1992) Chem Rev 92:1007

    Article  CAS  Google Scholar 

  5. Ikeda T, Hirano H, Aoki K (1989) Preparation of benzoylacrylic acid esters as drug and agrochemical intermediates. Jpn Kokai 63130564, 2 June 1988; Chem Abstr 110:7866

  6. Chosakon Y, Yamamoto N (1988) Process for the preparation of 3-benzoylacrylic acids as intermediates for food preservatives, perfumes, and drugs. Jpn Kokai 63104940, 10 May 1988; Chem Abstr 109:230551

  7. Nippon Synthetic Chemical Industry (1983) Benzoylacrylic acid esters as fungicides. Jpn Kokai 5838202, 5 Mar 1983; Chem Abstr 99:1818

  8. Nippon Synthetic Chemical Industry (1981) Benzoylacrylic acid esters as acaricides. Jpn Kokai 56127302, 6 Oct 1981; Chem Abstr 96:2180

  9. Iesce MR, Cermola F, Piazza A, Graziano ML, Scarpati R (1995) Synthesis 439

  10. Iesce MR, Cermola F, Graziano ML, Scarpati R (1994) Synthesis 944

  11. Li C-Q, Shi M (2003) Org Lett 5:4273

  12. Nair A, Sreekanth AR, Abhilash N, Biju AT, Devi BR, Menon RS, Rath NP, Srinivas R (2003) Synthesis 1895

  13. Bayat M, Imanieh H, Hassanzadeh F (2010) Tetrahedron Lett 51:1873

    Article  CAS  Google Scholar 

  14. Takahashi S, Ueda Y, Yanagida Y, Namito Y, Ohaska T, Watanabe K (1987) Process for the preparation of trans-β-benzoylacrylic acid esters. Eur Patent Appl EP204286, 10 Dec 1986; Chem Abstr 106:84179

  15. Kashyap B, Phukan P (2013) RSC Adv 3:15327

    Article  CAS  Google Scholar 

  16. Singh RSK, Kashyap B, Phukan P (2013) Tetrahedron Lett 54:6687

    Article  CAS  Google Scholar 

Download references

Acknowledgments

Financial Support from University Grants Commission, India (Grant No. 41-206/2012/SR), India, is gratefully acknowledged. BK thanks CSIR for the senior research fellowship.

Author information

Authors and Affiliations

  1. Department of Chemistry, Gauhati University, Guwahati, Assam, 781014, India

    Bishwapran Kashyap & Prodeep Phukan

Authors
  1. Bishwapran Kashyap
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Prodeep Phukan
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Prodeep Phukan.

Electronic supplementary material

Below is the link to the electronic supplementary material.

Supplementary material 1 (PDF 526 kb)

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Kashyap, B., Phukan, P. Poly(4-vinylpyridine-co-ethylvinylbenzene) as heterogeneous reusable catalyst for the synthesis of benzoyl fumarate. Monatsh Chem 147, 797–800 (2016). https://doi.org/10.1007/s00706-015-1531-7

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s00706-015-1531-7

Keywords

Search

Navigation