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Complexation of the divalent lead cation with cesium ionophore II: an extraction and DFT study

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Abstract

On the basis of extraction experiments in the two-phase water/nitrobenzene system and γ-activity measurements, we determined the very high stability constant of the cesium ionophore II–Pb2+ cationic complex dissolved in nitrobenzene saturated with water. Using quantum mechanical DFT calculations, the most probable structure of this complex species was derived.

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References

  1. Böhmer V (1995) Angew Chem Int Ed 34:713

    Article  Google Scholar 

  2. Gutsche CD (2008) Calixarenes: an introduction, 2nd edn. The Royal Society of Chemistry, Cambridge

    Google Scholar 

  3. Ungaro R, Casnati A, Ugozzoli F, Pochini A, Dozol JF, Hill C, Rouquette H (1994) Angew Chem Int Ed 33:1506

    Article  Google Scholar 

  4. Casnati A, Barboso S, Rouquette H, Schwing-Weill MJ, Arnaud-Neu F, Dozol JF, Ungaro R (2001) J Am Chem Soc 123:12182

    Article  CAS  Google Scholar 

  5. Makrlík E, Vaňura P (1985) Talanta 32:423

    Article  Google Scholar 

  6. Makrlík E, Vaňura P, Selucký P (2010) J Solut Chem 39:692

    Article  Google Scholar 

  7. Makrlík E, Vaňura P, Budka J, Selucký P (2010) Monatsh Chem 141:31

    Article  Google Scholar 

  8. Makrlík E, Vaňura P, Sedláková Z (2010) J Radioanal Nucl Chem 283:157

    Article  Google Scholar 

  9. Makrlík E, Vaňura P, Selucký P, Spíchal Z (2011) J Radioanal Nucl Chem 289:13

    Article  Google Scholar 

  10. Makrlík E, Čajan M, Budka J, Vaňura P (2011) Monatsh Chem 142:5

    Article  Google Scholar 

  11. Makrlík E, Spíchal Z, Vaňura P, Selucký P (2013) J Radioanal Nucl Chem 295:2135

    Article  Google Scholar 

  12. Romanovskiy VN, Smirnov IV, Babain VA, Todd TA, Herbst RS, Law JD, Brewer KN (2001) Solv Extr Ion Exch 19:1

    Article  CAS  Google Scholar 

  13. Law JD, Herbst RS, Todd TA, Romanovskiy VN, Babain VA, Esimantovskiy VM, Smirnov IV, Zaitsev BN (2001) Solvent Extr Ion Exch 19:23

    Article  CAS  Google Scholar 

  14. Makrlík E, Hálová J, Kyrš M (1984) Collect Czech Chem Commun 49:39

    Article  Google Scholar 

  15. Daňková M, Makrlík E, Vaňura P (1997) J Radioanal Nucl Chem 221:251

    Article  Google Scholar 

  16. Makrlík E, Vaňura P (2006) Monatsh Chem 137:157

    Article  Google Scholar 

  17. Makrlík E, Vaňura P (2010) J Radioanal Nucl Chem 285:683

    Article  Google Scholar 

  18. Makrlík E, Vaňura P (2012) J Radioanal Nucl Chem 293:931

    Article  Google Scholar 

  19. Makrlík E, Vaňura P, Budka J (2008) J Radioanal Nucl Chem 275:463

    Article  Google Scholar 

  20. Makrlík E, Vaňura P, Selucký P (2011) J Radioanal Nucl Chem 287:899

    Article  Google Scholar 

  21. Lee C, Yang W, Parr RG (1988) Phys Rev B 37:785

    Article  CAS  Google Scholar 

  22. Becke AD (1993) J Chem Phys 98:5648

    Article  CAS  Google Scholar 

  23. Frisch MJ, Trucks GW, Schlegel HB, Scuseria GE, Robb MA, Cheeseman JR, Scalmani G, Barone V, Mennucci B, Petersson GA, Nakatsuji H, Caricato M, Li X, Hratchian HP, Izmaylov AF, Bloino J, Zheng G, Sonnenberg JL, Hada M, Ehara M, Toyota K, Fukuda R, Hasegawa J, Ishida M, Nakajima T, Honda Y, Kitao O, Nakai H, Vreven T, Montgomery JA Jr, Peralta JE, Ogliaro F, Bearpark M, Heyd JJ, Brothers E, Kudin KN, Staroverov VN, Kobayashi R, Normand J, Raghavachari K, Rendell A, Burant JC, Iyengar SS, Tomasi J, Cossi M, Rega N, Millam JM, Klene M, Knox JE, Cross JB, Bakken V, Adamo C, Jaramillo J, Gomperts R, Stratmann RE, Yazyev O, Austin AJ, Cammi R, Pomelli C, Ochterski JW, Martin RL, Morokuma K, Zakrzewski VG, Voth GA, Salvador P, Dannenberg JJ, Dapprich S, Daniels AD, Farkas Ö, Foresman JB, Ortiz JV, Cioslowski J, Fox DJ (2009) Gaussian 09, Revision C.01. Gaussian Inc, Wallingford, CT

  24. Kříž J, Dybal J, Makrlík E, Vaňura P, Moyer BA (2011) J Phys Chem B 115:7578

    Article  Google Scholar 

  25. Toman P, Makrlík E, Vaňura P (2012) Monatsh Chem 143:985

    Article  CAS  Google Scholar 

  26. Makrlík E, Toman P, Vaňura P (2013) Monatsh Chem 144:919

    Article  Google Scholar 

  27. Hawthorne MF, Young DC, Andrews TD, Howe DV, Pilling RL, Pitts AD, Reintjes M, Warren LF, Wegner PA (1968) J Am Chem Soc 90:879

    Article  CAS  Google Scholar 

  28. Makrlík E (1992) Collect Czech Chem Commun 57:289

    Article  Google Scholar 

Download references

Acknowledgments

This work was supported by the Grant Agency of Faculty of Environmental Sciences, Czech University of Life Sciences, Prague, Project No.: 42900/1312/3114 “Environmental Aspects of Sustainable Development of Society”, and by the Czech Ministry of Education, Youth, and Sports (Project MSM 6046137307).

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Authors and Affiliations

  1. Faculty of Environmental Sciences, Czech University of Life Sciences, Prague, Czech Republic

    Emanuel Makrlík

  2. Institute of Chemical Technology, Prague, Czech Republic

    Stanislav Böhm & Petr Vaňura

Authors
  1. Emanuel Makrlík
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  2. Stanislav Böhm
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  3. Petr Vaňura
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Correspondence to Emanuel Makrlík.

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Makrlík, E., Böhm, S. & Vaňura, P. Complexation of the divalent lead cation with cesium ionophore II: an extraction and DFT study. Monatsh Chem 146, 1395–1399 (2015). https://doi.org/10.1007/s00706-014-1397-0

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  • DOI: https://doi.org/10.1007/s00706-014-1397-0

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