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A new neodymium(III)–calcium(II) one-dimensional coordination polymer constructed from dipicolinic acid: synthesis, crystal structure, spectroscopic and thermal analysis, and solution studies

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Abstract

A new heterometallic supramolecular coordination polymer, namely [(1-mimH)[Nd(pydc)3Ca(pydcH2)(H2O)2]·4H2O] n (where pydcH2 = pyridine-2,6-dicarboxylic acid (dipicolinic acid), 1-mim = 1-methylimidazole) has been prepared and characterized by elemental analysis, spectral (IR, UV–Vis), 1H NMR and 13C NMR spectroscopy, thermal analysis as well as single-crystal X-ray diffraction. The X-ray diffraction study demonstrates that the compound has a 1D network; the layers of this compound are connected by complicated hydrogen bonds to form 3D supramolecular architecture. The polymeric chain contains Nd(III) ions and Ca(II) ions bridged by (pydc)2− ligands. Each (pydc)2− ion is connected to one neodymium(III) ion as a tridentate ligand and one calcium ion via bridging carboxylate group. The equilibrium constants of dipicolinic acid and 1-methylimidazole, pydc/1-mim proton transfer system, as well as those of the complexes (binary, ternary, and quaternary) were investigated by potentiometric pH titration method.

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Authors and Affiliations

  1. Department of Chemistry, Faculty of Science, University of Kurdistan, Sanandaj, Iran

    Mohammad Ghadermazi & Arezoo Zahedi

  2. Department of Chemistry, Faculty of Science, Khorramabad Branch, Islamic Azad University, Khorramabad, Iran

    Zohreh Derikvand

  3. Department of Chemistry, Yasouj University, Yasouj, Iran

    Ardeshir Shokrollahi

  4. Department of Chemistry, University of Isfahan, Isfahan, 81746-73441, Iran

    Hadi Amiri Rudbari

  5. Department of Science and Research branch, Islamic Azad University, Fars, Iran

    Sara Nasiri

Authors
  1. Mohammad Ghadermazi
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  2. Zohreh Derikvand
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  3. Arezoo Zahedi
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  4. Ardeshir Shokrollahi
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  5. Sara Nasiri
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  6. Hadi Amiri Rudbari
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Correspondence to Mohammad Ghadermazi.

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Ghadermazi, M., Derikvand, Z., Zahedi, A. et al. A new neodymium(III)–calcium(II) one-dimensional coordination polymer constructed from dipicolinic acid: synthesis, crystal structure, spectroscopic and thermal analysis, and solution studies. Monatsh Chem 146, 1257–1266 (2015). https://doi.org/10.1007/s00706-014-1377-4

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  • DOI: https://doi.org/10.1007/s00706-014-1377-4

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