Skip to main content
SpringerLink
Log in

Dimeric and polymeric mercury(II) complexes containing 4-methyl-1,2,4-triazole-3-thiol ligand: X-ray studies, spectroscopic characterization, and thermal analyses

  • Original Paper
  • Published:
Monatshefte für Chemie - Chemical Monthly Aims and scope Submit manuscript

Abstract

The polymer complex [Hg(μ-mptrz)2] n and two binuclear complexes of {[H2en][Hg2(mptrz)4(μ-Br)2]} and {[H2en][Hg2(mptrz)4(μ-I)2]} were prepared from the reaction of 4-methyl-1,2,4-triazole-3-thiol (Hmptrz) and ethylene diamine (en) with HgCl2, HgBr2, and HgI2 in CH3OH, respectively. Complex [Hg(μ-mptrz)2] n was also prepared from the reaction of 4-methyl-1,2,4-triazole-3-thiol and ethylene diamine with Hg(OAc)2 and Hg(SCN)2 in CH3OH and Hg(NO3)2·H2O in a mixture of CH3OH/H2O. Analysis of these complexes was done by CHN elemental analysis, IR, UV–Vis, 1H and 13C NMR, and luminescence spectroscopy, as well as single-crystal X-ray diffraction. Thermal stabilities of these complexes were also studied by TGA/DTA analyses.

Graphical abstract

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Subscribe and save

Springer+ Basic
$34.99 /Month
  • Get 10 units per month
  • Download Article/Chapter or eBook
  • 1 Unit = 1 Article or 1 Chapter
  • Cancel anytime
Subscribe now

Buy Now

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9
Fig. 10
Fig. 11

Similar content being viewed by others

References

  1. Bell NA, Clegg W, Creighton JR, Raper ES (2000) Inorg Chim Acta 303:12

    Article  CAS  Google Scholar 

  2. Popović Z, Matković-Ćalogović D, Soldin Ž, Pavlović G, Davidović N, Vikić-Topić D (1999) Inorg Chim Acta 294:35

    Article  Google Scholar 

  3. Steele RA, Opella SJ (1997) Biochem 36:6885

    Article  CAS  Google Scholar 

  4. Dance IG (1986) Polyhedron 5:1037

    Article  CAS  Google Scholar 

  5. Cheesman BV, Arnold AP, Rabenstein DZ (1988) J Am Chem Soc 110:6359

    Article  CAS  Google Scholar 

  6. Nielsen KB, Atkin CL, Winge DR (1985) J Biol Chem 260:5342

    Google Scholar 

  7. Samiei Paqhaleh DM, Hashemi L, Amani V, Morsali A, Aminjanov AA (2013) Inorg Chim Acta 407:1

    Article  Google Scholar 

  8. Samiei Paqhaleh DM, Aminjanov AA, Amani V, Morsali A (2014) J Inorg Organomet Polym Mater 24:340

    Article  Google Scholar 

  9. Wang YL, Zhang N, Liu QY, Shan ZM, Cao R, Wang MS, Luo JJ, Yang EL (2011) Cryst Growth Des 11:130

    Article  CAS  Google Scholar 

  10. Jiang YL, Wang YL, Lin JX, Liu QY, Lu ZH, Zhang N, Wei JJ, Li LQ (2011) CrystEngComm 13:1697

    Article  CAS  Google Scholar 

  11. Wang YL, Jiang YL, Liu QY, Wei JJ, Li LQ (2012) Aust J Chem 65:50

    Article  CAS  Google Scholar 

  12. Kodcharat K, Pakawatchai C, Saithong S (2013) Acta Crystallogr E69:m265

    Google Scholar 

  13. Ma C, Tian G, Zhang R (2006) J Inorg Organomet Polym Mater 16:139

    Article  CAS  Google Scholar 

  14. Jolley J, Cross WI, Pritchard RG, McAuliffe CA, Nolan KB (2001) Inorg Chim Acta 315:36

    Article  CAS  Google Scholar 

  15. Bellamy LJ (1975) The infrared spectra of complex molecules, 3rd edn. Chapman and Hall, London

    Book  Google Scholar 

  16. Brill TB, Wertz DW (1970) Inorg Chem 9:2692

    Article  CAS  Google Scholar 

  17. Giusti A, Peyronel G (1982) Spectrochim Acta A 38:975

    Article  Google Scholar 

  18. Barr RM, Goldstein M, Unsworth WD (1974) J Cryst Mol Struct 4:165

    Article  CAS  Google Scholar 

  19. Allman T, Goel RG, Pilon P (1979) Spectrochim Acta A 35:923

    Article  Google Scholar 

  20. Alizadeh R, Amani V, Farshady AA, Khavasi HR (2010) J Coord Chem 63:2122

    Article  CAS  Google Scholar 

  21. Nakamoto K (2009) Infrared and Raman Spectra of Inorganic and Coordination Compounds. Part B: Application in Coordination, Organometallic and Bioinorganic Chemistry. John Wiley and Sons, New York

    Google Scholar 

  22. Mendizabal F, Burgos D, Azar CO (2008) Chem Phys Lett 463:272

    Article  CAS  Google Scholar 

  23. Horváth O, Vogler A (1994) Inorg Chim Acta 221:79

    Article  Google Scholar 

  24. Abedi A, Safari N, Amani V, Khavasi HR (2012) J Coord Chem 65:325

    Article  CAS  Google Scholar 

  25. Al-Hashemi R, Safari N, Amani V, Amani S, Ng SW (2014) J Iran Chem Soc 11:341

    Article  CAS  Google Scholar 

  26. Amani V, Abedi A, Safari N (2012) Monatsh Chem 143:589

    Article  CAS  Google Scholar 

  27. Abedi A, Amani V, Safari N (2012) Main Group Chem 11:223

    CAS  Google Scholar 

  28. Amani V, Safari N, Notash B (2013) J Iran Chem Soc 10:751

    Article  CAS  Google Scholar 

  29. Mahmoudi G, Morsali A, Zeller M (2009) Inorg Chim Acta 362:217

    Article  CAS  Google Scholar 

  30. Mahmoudi G, Morsali A, Zhu LG (2007) Polyhedron 26:2885

    Article  CAS  Google Scholar 

  31. Collins LW, Gibson EK, Wendelandt WW (1975) Thermochim Acta 11:177

    Article  CAS  Google Scholar 

  32. Askarinejad A, Morsali A (2009) Chem Eng J 153:183

    Article  CAS  Google Scholar 

  33. Bell NA, Branston TN, Clegg W, Creighton JR, Cucurull-Sánchez L, Elsegood MRJ, Raper ES (2000) Inorg Chim Acta 303:220

    Article  CAS  Google Scholar 

  34. Bell NA, Branston TN, Clegg W, Parker L, Raper ES, Sammon C, Constable CP (2001) Inorg Chim Acta 319:30

    Article  Google Scholar 

  35. Tirloni B, Back DF, Burrow RA, Oliveira GNM, Villetti MA, Lang ES (2010) J Braz Chem Soc 21:1230

    Article  CAS  Google Scholar 

  36. Isaia F, Aragoni MC, Arca M, Caltagirone C, Castellano C, Demartin F, Garau A, Lippolis V, Pintus A (2011) Dalton Trans 40:4505

    Article  CAS  Google Scholar 

  37. Sheldrick GM (1998) SADABS. Bruker AXS, Madison

    Google Scholar 

  38. Bruker (2005) APEX2 Software Package, vers 20-1. Bruker AXS Inc, Madison

    Google Scholar 

  39. Sheldrick GM (1998) SHELXTL (Version 51), Structure Determination Software Suite. Bruker AXS, Madison

    Google Scholar 

  40. Sheldrick GM (2008) Acta Crystallogr A64:112

    Article  Google Scholar 

  41. Farrugia LJ (1999) J Appl Crystallogr 32:837

    Article  CAS  Google Scholar 

  42. Farrugia LJ (1997) J Appl Crystallogr 30:565

    Article  CAS  Google Scholar 

  43. Mercury 1.4.1 (2001–2005) Copyright Cambridge Crystallographic Data Center, 12 Union Road, Cambridge CB2 1EZ, UK

Download references

Acknowledgments

We would like to thank the University of Kurdistan and Islamic Azad University, Yadegar-e-Imam Khomeini (RAH) Branch, for financial support.

Author information

Authors and Affiliations

  1. Department of Chemistry, Faculty of Science, University of Kurdistan, Sanandaj, Iran

    Mohammad Taheriha & Mohammad Ghadermazi

  2. Department of Chemistry, Yadegar-e-Imam Khomeini (RAH) Branch, Islamic Azad University, Tehran, Iran

    Vahid Amani

Authors
  1. Mohammad Taheriha
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Mohammad Ghadermazi
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Vahid Amani
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding authors

Correspondence to Mohammad Ghadermazi or Vahid Amani.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Taheriha, M., Ghadermazi, M. & Amani, V. Dimeric and polymeric mercury(II) complexes containing 4-methyl-1,2,4-triazole-3-thiol ligand: X-ray studies, spectroscopic characterization, and thermal analyses. Monatsh Chem 146, 559–569 (2015). https://doi.org/10.1007/s00706-014-1333-3

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s00706-014-1333-3

Keywords

Search

Navigation