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Photoinduced processes of 2,1,3-benzoselena(thia)diazole derivatives in dimethylsulfoxide: an in situ EPR spin trapping study

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Abstract

The ability of 2,1,3-benzoselena(thia)diazole derivatives to generate paramagnetic intermediates upon monochromatic excitation (λ max = 365 nm) under different experimental conditions was monitored via EPR spin trapping. The photoinduced activation of molecular oxygen leading to the production of superoxide radical anions, along with other oxygen-, carbon-, or nitrogen-centered radicals originating from the solvent or the solute was evidenced via the identification of the corresponding spin adducts.

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Acknowledgments

This work was supported by the Research and Development Agency of the Slovak Republic (Contract Nos. APVV-0339-10, APVV-0038-11) and the Scientific Grant Agency of the Slovak Republic (Projects VEGA/1/0289/12, 1/0829/14). Phil Grier is gratefully acknowledged for helpful discussion.

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Authors and Affiliations

  1. Institute of Physical Chemistry and Chemical Physics, Faculty of Chemical and Food Technology, Slovak University of Technology in Bratislava, Radlinského 9, 812 37, Bratislava, Slovakia

    Zuzana Barbieriková, Andrej Staško, Jana Semanová, Dana Dvoranová & Vlasta Brezová

  2. Institute of Analytical Chemistry, Faculty of Chemical and Food Technology, Slovak University of Technology in Bratislava, Radlinského 9, 812 37, Bratislava, Slovakia

    Michal Karabín

  3. Institute of Chemistry, Slovak Academy of Sciences, Dúbravská cesta 9, 845 38, Bratislava, Slovakia

    Maroš Bella

  4. Institute of Organic Chemistry, Catalysis and Petrochemistry, Faculty of Chemical and Food Technology, Slovak University of Technology in Bratislava, Radlinského 9, 812 37, Bratislava, Slovakia

    Viktor Milata

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  1. Zuzana Barbieriková
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  2. Andrej Staško
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Correspondence to Vlasta Brezová.

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Dedicated to the memory of Professor Ladislav Valko.

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Barbieriková, Z., Staško, A., Semanová, J. et al. Photoinduced processes of 2,1,3-benzoselena(thia)diazole derivatives in dimethylsulfoxide: an in situ EPR spin trapping study. Monatsh Chem 145, 1449–1460 (2014). https://doi.org/10.1007/s00706-014-1236-3

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  • DOI: https://doi.org/10.1007/s00706-014-1236-3

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