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Tetraphenolate c-methylcalix[4]resorcinarene as a new heterogeneous phase transfer catalyst for ring-opening of triaryl substituted pyrylium salts in aqueous biphasic medium

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Abstract

This study reports, for the first time, the application of water-insoluble tetraphenolate c-methylcalix[4]resorcinarene as an efficient and heterogeneous phase transfer catalyst at room temperature. This supramolecule could facilitate the nucleophilic reactions through the formation of a host–guest complex in the organic-aqueous interfacial layer. Moreover, the recovered catalyst can be used for several times without serious decrease in activity.

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Acknowledgments

This work was supported by the Research Council at the University of Shahid Chamran.

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Authors and Affiliations

  1. Department of Chemistry, Faculty of Science, Shahid Chamran University, Ahvaz, Iran

    Arash Mouradzadegun, Fatemeh Abadast & Somayeh Elahi

Authors
  1. Arash Mouradzadegun
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  2. Fatemeh Abadast
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  3. Somayeh Elahi
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Corresponding author

Correspondence to Arash Mouradzadegun.

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Mouradzadegun, A., Abadast, F. & Elahi, S. Tetraphenolate c-methylcalix[4]resorcinarene as a new heterogeneous phase transfer catalyst for ring-opening of triaryl substituted pyrylium salts in aqueous biphasic medium. Monatsh Chem 145, 1663–1667 (2014). https://doi.org/10.1007/s00706-014-1235-4

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  • DOI: https://doi.org/10.1007/s00706-014-1235-4

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