Abstract
The tin-rich stannides BaRh5–x Sn9 and BaRu5–x Sn9 were synthesized by direct reactions of the elements in sealed niobium or tantalum tubes in muffle furnaces. Their structures were refined from X-ray single-crystal diffractometer data: BaCo4.7Ge9 type, Pnma, Z = 4, a = 1,553.44(8) pm, b = 438.38(2) pm, c = 1,861.5(1) pm, wR = 0.0558, 2,787 F 2 values for BaRh4.43Sn9, a = 1,554.09(6) pm, b = 438.44(1) pm, c = 1,873.44(5) pm, wR = 0.0589, 2,184 F 2 values for BaRh4.68Sn9, and a = 1,560.7(2) pm, b = 440.24(4) pm, c = 1,869.0(3) pm, wR = 0.0674, 2,197 F 2 values for BaRu4.57Sn9 with 93 variables per refinement. The Rh5 and Ru5 sites show small defects. The shortest interatomic distances occur for Ru–Sn and Rh–Sn, leading to Ru@Sn7 and Rh@Sn7 building units that derive from an octahedron by replacing one apex by a pair of tin atoms. These units condense by common triangular and rectangular faces forming a three-dimensional network in which the barium atoms fill slightly distorted pentagonal prismatic voids.
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Skolozdra RV (1997) Stannides of rare earth and transition metals. In: Gschneidner KA Jr, Eyring L (eds), Handbook on the physics and chemistry of rare earths, vol 24. Elsevier Science, Amsterdam, Chapter 164, p 399
Villars P, Cenzual K (2013) Pearson’s crystal data–crystal structure database for inorganic compounds, Release 2013/14. ASM International, Materials Park
Niepmann D, Pöttgen R, Poduska KM, DiSalvo F, Trill H, Mosel BD (2001) Z Naturforsch 56b:1
Niepmann D, Pöttgen R, Künnen B, Kotzyba B, Rosenhahn C, Mosel BD (1999) Chem Mater 11:1597
Routsi CD, Yakinthos JK, Gamari-Seale H (1992) J Magn Magn Mater 117:79
Chevalier B, Sebastian CP, Pöttgen R (2006) Solid State Sci 8:1000
Gamża M, Schnelle W, Gumeniuk R, Prots Y, Ślebarski A, Rosner H, Grin Y (2009) J Phys Condens Matter 21:325601
Anand VK, Adroja DT, Hillier AD, Kockelmann W, Fraile A, Strydom AM (2011) J Phys Condens Matter 23:276001
Wu Z, Hoffmann R-D, Pöttgen R (2002) Z Anorg Allg Chem 628:1484
Wu Z, Eckert H, Senker J, Johrendt D, Kotzyba G, Mosel BD, Trill H, Hoffmann R-D, Pöttgen R (2003) J Phys Chem B 107:1943
Dinges T, Pöttgen R (2010) Z Kristallogr 225:405
Sreeraj P, Johrendt D, Müller H, Hoffmann R-D, Wu Z, Pöttgen R (2005) Z Naturforsch 60b:933
Sreeraj P, Kurowski D, Hoffmann R-D, Wu Z, Pöttgen R (2005) J Solid State Chem 178:3420
Pöttgen R, Wu Z, Hoffmann R-D, Kotzyba G, Trill H, Senker J, Johrendt D, Mosel BD, Eckert H (2002) Heteroatom Chem 13:506
Pöttgen R, Dinges T, Eckert H, Sreeraj P, Wiemhöfer H-D (2010) Z Phys Chem 224:1475
Schlüter M, Kunst A, Pöttgen R (2002) Z Anorg Allg Chem 628:2641
Cooper AS (1980) Mater Res Bull 15:799
Hodeau JL, Marezio M, Remeika JP, Chen CH (1982) Solid State Commun 42:97
Miraglia S, Hodeau JL, Marezio M, Laviron C, Ghedira M, Espinosa GP (1986) J Solid State Chem 63:358
Hoffmann R-D, Kußmann D, Rodewald UC, Pöttgen R, Rosenhahn C, Mosel BD (1999) Z Naturforsch 54b:709
Schwickert C, Pöttgen R (2013) Z Naturforsch 68b:17
Nasir N, Melnychenko-Koblyuk N, Grytsiv A, Rogl P, Bauer E, Royanian E, Michor H, Hilscher G, Giester G (2009) Intermetallics 17:471
Palatinus L, Chapuis G (2007) J Appl Crystallogr 40:786
Petricek V, Dusek M, Palatinus L (2006) Structure determination software programs. Institute of Physics, University of Prague, Prague (Czech Republic)
Hlukhyy V, Fässler TF, Claus P (2009) Z Anorg Allg Chem 635:708
Schwickert C, Pöttgen R (2014) Z Naturforsch. doi:10.5560/ZNB.2014-4008
Emsley J (1999) The elements. Oxford University Press, Oxford
Riecken JF, Hermes W, Chevalier B, Hoffmann R-D, Schappacher FM, Pöttgen R (2007) Z Anorg Allg Chem 633:1094
Pöttgen R, Hoffmann R-D, Sampathkumaran EV, Das I, Mosel BD, Müllmann R (1997) J Solid State Chem 134:326
Donohue J (1974) The structures of the elements. Wiley, New York
Pöttgen R (2006) Z Naturforsch 61b:677
Schwomma O, Nowotny H, Wittmann A (1964) Monatsh Chem 95:1538
Eisenmann B, Schäfer H (1986) J Less-Common Met 123:89
Reichelt W, Söhnel T, Rademacher O, Oppermann H, Simon A, Köhler J, Mattausch HJ (1995) Angew Chem 107:2307
Pöttgen R, Gulden T, Simon A (1999) GIT Labor-Fachz 43:133
Yvon K, Jeitschko W, Parthé E (1977) J Appl Crystallogr 10:73
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This work was financially supported by the Deutsche Forschungsgemeinschaft.
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Schwickert, C., Rodewald, U.C. & Pöttgen, R. Ba@Sn10 and Ru@Sn7/Rh@Sn7 polyhedra as basic building units in the stannides BaT 5–x Sn9 (T = Ru, Rh). Monatsh Chem 145, 1227–1233 (2014). https://doi.org/10.1007/s00706-014-1209-6
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DOI: https://doi.org/10.1007/s00706-014-1209-6