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Synthesis of 1,1′-binaphthyl derivatives by Miyaura-Suzuki cross-coupling in cholesteric liquid crystal phase

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Abstract

We synthesized 1,1′-binaphthyl and 2-substituted-1,1′-binaphthyl by the Miyaura-Suzuki cross-coupling reaction in cholesteric liquid crystal (CLC) media. The 1H and 13C NMR and UV–Vis absorption spectra of the compounds thus prepared were examined. The liquid crystallinity of the CLC media before and after the reaction was confirmed by differential scanning calorimetry, polarizing optical microscopy, and visual contact in order to characterize the reaction in a CLC phase.

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Acknowledgments

We would like to thank the Glass Work Shop and Chemical Analysis Division Research Facility Center for Science and Technology of the University of Tsukuba for glass work and NMR, GC–MS, and DSC measurements.

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Authors and Affiliations

  1. Division of Materials Science, Faculty of Pure and Applied Sciences, University of Tsukuba, Tsukuba, Ibaraki, 305-8573, Japan

    Tomokazu Iseki & Hiromasa Goto

Authors
  1. Tomokazu Iseki
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  2. Hiromasa Goto
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Correspondence to Hiromasa Goto.

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Iseki, T., Goto, H. Synthesis of 1,1′-binaphthyl derivatives by Miyaura-Suzuki cross-coupling in cholesteric liquid crystal phase. Monatsh Chem 145, 1145–1149 (2014). https://doi.org/10.1007/s00706-014-1199-4

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  • DOI: https://doi.org/10.1007/s00706-014-1199-4

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