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GaCl3-catalyzed activation of alkynyl glycosides for the synthesis of O-glycosides

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Abstract

A catalytic amount of GaCl3 (5 mol%) was found to activate alkynyl glycosides effectively under mild reaction conditions to furnish a variety of O-glycosides in good yields with high β-selectivity.

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Acknowledgments

NNY, MKG, and NS thank CSIR, New Delhi for the award of research fellowships.

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Authors and Affiliations

  1. CSIR-Natural Product Chemistry, Indian Institute of Chemical Technology, Hyderabad, 500 607, India

    Jhillu S. Yadav, Nagendra N. Yadav, Manoj K. Gupta, Nikhil Srivastava & Basi V. Subba Reddy

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  1. Jhillu S. Yadav
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  2. Nagendra N. Yadav
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  3. Manoj K. Gupta
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  4. Nikhil Srivastava
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  5. Basi V. Subba Reddy
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Correspondence to Jhillu S. Yadav.

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Yadav, J.S., Yadav, N.N., Gupta, M.K. et al. GaCl3-catalyzed activation of alkynyl glycosides for the synthesis of O-glycosides. Monatsh Chem 145, 517–520 (2014). https://doi.org/10.1007/s00706-013-1091-7

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  • DOI: https://doi.org/10.1007/s00706-013-1091-7

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