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Synthesis of a novel piperidine-functionalized poly(ethylene glycol) bridged dicationic ionic liquid and its application in one-pot synthesis of substituted 2-amino-2-chromenes and 3,4-dihydropyrano[3,2-c]chromenes in aqueous media

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Abstract

A novel piperidine-functionalized poly(ethylene glycol) bridged dicationic ionic liquid was prepared and identified. It was used as a recyclable catalyst for the synthesis of substituted 2-amino-2-chromenes and 3,4-dihydropyrano[3,2-c]chromenes with excellent yields through a one-pot three-component reaction of aromatic aldehydes, malononitrile, and activated phenols in aqueous media. This environmentally benign protocol was found to be fairly efficient and offer wide substrate flexibility. The basic ionic liquid could be reused several times without any obvious loss of catalytic activity.

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Acknowledgments

This project was financially sponsored and supported by the National Natural Science Foundation of China (No. 21002050), the Doctoral Fund of the Ministry of Education of China for New Teachers (No. 200802881029), the Zijin Star Project and the Excellence Initiative Project of NUST.

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Authors and Affiliations

  1. School of Chemical Engineering, Nanjing University of Science and Technology, Nanjing, 210094, China

    Yinglei Wang, Jun Luo, Tantan Xing & Zuliang Liu

Authors
  1. Yinglei Wang
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  2. Jun Luo
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  3. Tantan Xing
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  4. Zuliang Liu
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Corresponding author

Correspondence to Jun Luo.

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Wang, Y., Luo, J., Xing, T. et al. Synthesis of a novel piperidine-functionalized poly(ethylene glycol) bridged dicationic ionic liquid and its application in one-pot synthesis of substituted 2-amino-2-chromenes and 3,4-dihydropyrano[3,2-c]chromenes in aqueous media. Monatsh Chem 144, 1871–1876 (2013). https://doi.org/10.1007/s00706-013-1066-8

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  • DOI: https://doi.org/10.1007/s00706-013-1066-8

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