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Syntheses, structures, and photoluminescence properties of Zn(II)/Cd(II) supramolecular architectures based on 1,5-naphthalenedisulfonate and 1,10-phenanthroline ligands

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Abstract

Two new supramolecular transition metal compounds, [Zn(phen)2(1,5-NDS)(H2O)] and [Cd(phen)2(1,5-NDS)]n (1,5-NDS = 1,5-naphthalenedisulfonate, phen = 1,10-phenanthroline), were obtained under hydrothermal/solvothermal conditions and structurally characterized by elemental analysis, IR, PXRD, TG-DSC, and single-crystal X-ray determination. They represent the first examples of Zn(II)/Cd(II) supramolecular compounds based on the 1,5-NDS/phen system. The Zn compound exhibits a 3D supramolecular structure via hydrogen bond (O–H⋯O and C–H⋯O) and π–π interactions. The Cd compound is a 3D supramolecular framework generated by 1D coordinated chains through a hydrogen bond (C–H⋯O) and π–π interactions. In addition, photoluminescence properties for both have been discussed. [Zn(phen)2(1,5-NDS)(H2O)] shows an emission peak at 420 nm (λ ex = 342 nm), and [Cd(phen)2(1,5-NDS)] n displays a strong emission peak at 388 nm with a shoulder peak at 369 nm (λ ex = 332 nm).

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Acknowledgments

This work was supported by the National Natural Science Foundation of China (No. 20671038) and Jiangsu Key Laboratory for the Chemistry of Low-Dimensional Materials (no. JSKC11098).

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Authors and Affiliations

  1. Jiangsu Key Laboratory for the Chemistry of Low-Dimensional Materials, Huaiyin Normal University, Huaian, 223300, People’s Republic of China

    Yulan Zhu & Kuirong Ma

  2. Faculty of Chemistry, Northeast Normal University, Changchun, 130024, People’s Republic of China

    Yulan Zhu, Shuai Shao, Huichao Zhao & Yongqing Qiu

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  1. Yulan Zhu
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  2. Shuai Shao
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  3. Kuirong Ma
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  4. Huichao Zhao
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  5. Yongqing Qiu
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Corresponding author

Correspondence to Yulan Zhu.

Electronic supplementary material

Below is the link to the electronic supplementary material.

CCDC 872875 and 878056 contain the supplementary crystallographic data for 1 and 2. These data can be obtained free of charge via http://www.ccdc.cam.ac.uk, or from the Cambridge Crystallographic Data Centre, 12 Union Road, Cambridge CB2 1EZ, UKfax: (+44) 1223-336-033; or e-mail: deposit@ccdc.cam.ac.uk.

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Zhu, Y., Shao, S., Ma, K. et al. Syntheses, structures, and photoluminescence properties of Zn(II)/Cd(II) supramolecular architectures based on 1,5-naphthalenedisulfonate and 1,10-phenanthroline ligands. Monatsh Chem 144, 1507–1512 (2013). https://doi.org/10.1007/s00706-013-1037-0

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  • DOI: https://doi.org/10.1007/s00706-013-1037-0

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