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Crystal structure and vibrational spectra of hydrazinium(+1) fluorocadmate(II)

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Abstract

X-ray crystal structure determination at 200 K revealed that N2H5CdF3 crystallizes in the orthorhombic space group Pnam, with unit cell dimensions a = 1,421.0(2), b = 694.29(11), c = 447.52(7) pm. The structure consists of N2H5 + cations and double Cd–F chains interconnected by a hydrogen bonding network. The N–N stretching vibration in N2H5CdF3 is active in infrared and Raman spectroscopy with an N–N stretching infrared band at 1,002 cm−1 and a Raman band at 1,008 cm−1.

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Acknowledgments

Financial support of the Slovenian Research Agency (ARRS) is acknowledged.

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Authors and Affiliations

  1. Jožef Stefan Institute, Ljubljana, Slovenia

    Clara Sousa-Silva, Gleb Veryasov, Evgeny Goreshnik, Maja Ponikvar & Adolf Jesih

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  1. Clara Sousa-Silva
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  2. Gleb Veryasov
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  3. Evgeny Goreshnik
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  4. Maja Ponikvar
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  5. Adolf Jesih
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Correspondence to Adolf Jesih.

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Sousa-Silva, C., Veryasov, G., Goreshnik, E. et al. Crystal structure and vibrational spectra of hydrazinium(+1) fluorocadmate(II). Monatsh Chem 144, 1455–1459 (2013). https://doi.org/10.1007/s00706-013-1036-1

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  • DOI: https://doi.org/10.1007/s00706-013-1036-1

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