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Preparation, spectroscopic, structural, and thermal characterization of vanadium complexes with 2-quinaldic acid

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Abstract

The reactions of vanadyl sulfate pentahydrate or vanadyl acetylacetonate with 2-quinaldic acid (2-quinH) were investigated. Six new vanadium complexes [VO(2-quin)2], [VO(2-quin)2]·CHCl3, [VO(2-quin)2(py)], [VO(2-quin)2(4-pic)], [VO2(2-quin)(4-pic)], and [VO(2-quin)2(H2O)]·2DMSO were prepared and characterized by infrared spectroscopy and thermal analysis (TGA/DTA). The vanadium(V) complex [VO2(2-quin)(4-pic)] was obtained accidently by the oxidation of [VO(2-quin)2], dissolved in 4-picoline, upon prolonged standing in air. The crystal structure of [VO2(2-quin)(4-pic)] was determined by single-crystal X-ray structural analysis. The coordination environment of the vanadium(V) ion in [VO2(2-quin)(4-pic)] is intermediate between a trigonal bipyramid and a square pyramid, with two oxo O atoms in the cis position, one 2-quinaldate ligand bound in an N,O-chelated mode, and one 4-picoline molecule. The compound crystallizes in the P21 /a space group of the monoclinic crystal system, with the parameters of the unit cell a = 7.2691(7) Å, b = 13.0769(12) Å, c = 15.7840(15) Å, β = 91.252(8)°, Z = 4.

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Acknowledgments

This research was supported by the Ministry of Science, Education and Sports of the Republic of Croatia (grant no. 119-1193079-1332).

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Authors and Affiliations

  1. Laboratory of General and Inorganic Chemistry, Department of Chemistry, Faculty of Science, University of Zagreb, Horvatovac 102a, 10000, Zagreb, Croatia

    Neven Smrečki, Boris-Marko Kukovec & Zora Popović

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  1. Neven Smrečki
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  2. Boris-Marko Kukovec
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  3. Zora Popović
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Correspondence to Boris-Marko Kukovec.

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Smrečki, N., Kukovec, BM. & Popović, Z. Preparation, spectroscopic, structural, and thermal characterization of vanadium complexes with 2-quinaldic acid. Monatsh Chem 143, 1471–1477 (2012). https://doi.org/10.1007/s00706-012-0813-6

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