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Synthesis of β-amino alcohols catalyzed by poly(vinyl chloride)-supported Schiff base metal complexes

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Abstract

Eight transition metal complexes of various Schiff bases supported on poly(vinyl chloride) (PVC) were prepared and characterized. These metal complexes were screened as heterogeneous catalysts in the synthesis of β-amino alcohols by ring opening of epoxides with amines. The best catalyst was identified as a Ni(II) complex of PVC-supported 2-[(2-aminoethylimino)methyl]phenol and it was used in the synthesis of a number of different β-amino alcohols. The catalyst was found to be reusable for up to five cycles.

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Acknowledgments

The authors would like to acknowledge Defense Research and Development Organization, India for financial support and the NMR research centre at the Indian Institute of Science, Bangalore for NMR spectral analysis.

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Authors and Affiliations

  1. Department of Applied Chemistry, Cochin University of Science and Technology, Kochi, Kerala, India

    G. Rajesh Krishnan, K. Sapna Kajal & Krishnapillai Sreekumar

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  1. G. Rajesh Krishnan
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  2. K. Sapna Kajal
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  3. Krishnapillai Sreekumar
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Correspondence to Krishnapillai Sreekumar.

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Krishnan, G.R., Kajal, K.S. & Sreekumar, K. Synthesis of β-amino alcohols catalyzed by poly(vinyl chloride)-supported Schiff base metal complexes. Monatsh Chem 143, 637–642 (2012). https://doi.org/10.1007/s00706-011-0628-x

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  • DOI: https://doi.org/10.1007/s00706-011-0628-x

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