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Synthesis, characterization, and crystal structural study of the iron(II) 4,4′-bithiazole complex [Fe(C6H4N2S2)3]2+(NO3 −)2

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Abstract

The complex [Fe(C6H4N2S2)3]2+(NO −3 )2 was prepared from the reaction of 4,4′-bithiazole with Fe(NO3)3·9H2O in methanol. It was characterized by IR, UV-Vis, luminescence, 1H NMR and 13C NMR spectroscopy, and X ray crystallography. The structure was solved in the orthorhombic space group P212121 with a = 12.1500(5), b = 12.8434(6), c = 16.2222(7) Å, V = 2531.43(19) Å3, Z = 4, and with wR 2  = 0.0897.

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Acknowledgments

We would like to thank the Graduate Study Councils of Shahid Beheshti University and Islamic Azad University, North Tehran Branch, for financial support.

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Authors and Affiliations

  1. Department of Chemistry, Shahid Beheshti University, G.C., Evin, Tehran, 983963113, Iran

    Vahid Amani & Nasser Safari

  2. Department of Chemistry, North Tehran Branch, Islamic Azad University, Tehran, Iran

    Anita Abedi

Authors
  1. Vahid Amani
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  2. Anita Abedi
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  3. Nasser Safari
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Correspondence to Nasser Safari.

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Amani, V., Abedi, A. & Safari, N. Synthesis, characterization, and crystal structural study of the iron(II) 4,4′-bithiazole complex [Fe(C6H4N2S2)3]2+(NO3 −)2 . Monatsh Chem 143, 589–593 (2012). https://doi.org/10.1007/s00706-011-0607-2

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  • DOI: https://doi.org/10.1007/s00706-011-0607-2

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