Abstract
Adsorption of an octacationic tetrapyrrole, octakis(2-trimethylammoniumethylsulfanyl)porphyrazinatocobalt octaiodide (QCoPz), from aqueous solutions on to negatively charged bentonite was investigated. Effects of temperature, dye concentration, solid concentration, and contact time on adsorption were determined. Zeta potential and ion-release measurements were also used as supporting experiments. Experimental data were analyzed using four adsorption kinetic models; a pseudo second-order kinetic model resulted in better correlation with experimental results than the others. Experimental equilibrium data were analyzed by non-linear regression using five adsorption isotherm models with two, three, or four terms. Free energies, enthalpies, and entropies for the adsorption process were determined. The results indicated that adsorption of QCoPz on bentonite was exothermic and spontaneous in nature. FT-IR spectroscopy of the composite and its desorptive behavior were also investigated to identify the mechanism of adsorption. The novel QCoPz–bentonite composites obtained are likely to be used in “green chemistry” and in a wide range of optical and/or catalytic applications, especially those crucially important in the petroleum and pulp/paper industries for waste water cleaning (destruction of mercaptans, sulfides, phenol, and halogenated aromatics, etc.) and removal of bad odor.
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Stuzhin PA, Ercolani C (2003) In: Kadish KM, Smith KM, Guilard R (eds) The porphyrin handbook, vol 15. Academic Press, New York
Leznoff CC, Lever ABP (1989–1996) In: Phthalocyanines: properties and applications, vols 1–4. VCH, Weinheim
Arslanoğlu Y, Sevim AM, Hamuryudan E, Gül A (2006) Dyes Pigment 68:129
McKeown NB (1998) Phthalocyanine materials: synthesis structure and function. Cambridge University Press, Cambridge
Ogawa M, Kuroda K (1995) Chem Rev 95:399
Takagi K, Shichi T (2000) In: Ramamurthy V, Schanze KS (eds) Solid state and surface photochemistry, vol 5. Marcel Dekker, New York
Drain CM, Hupp JT, Suslick KS, Wasielewski MR, Chen X (2002) J Porphyr Phthalocyanines 6:243
Lindsay-Smith JR (1994) In: Sheldon RA (ed) Metalloporphyrins in catalytic oxidations, chap 11. Marcel Dekker, New York
Wöhrle D, Suvorova O, Gerdes R, Bartels O, Lapok L, Baziakina N, Makarov S, Slodek A (2004) J Porphyr Phthalocyanines 8:1020
Barloy L, Battioni P, Mansuy D (1990) J Chem Soc Chem Commun 19:1365
Bedioui F (1995) Coord Chem Rev 144:39
Sakoda K, Kominami K (1993) Chem Phys Lett 216:270
Sasai R, Sugiyama D, Takahashi S, Tong Z, Shichi T, Itoh H, Takagi K (2003) J Photochem Photobiol A 155:223
Takagi S, Shimada T, Yui T, Inoue H (2001) Chem Lett 2:128
Takagi S, Shimada T, Eguchi M, Yui T, Yoshida H, Tryk DA, Inoue H (2002) Langmuir 18:2265
Van Damme H, Crespin M, Obrecht F, Cruz MI, Fripiat JJ (1978) J Colloid Interface Sci 66:43
Elvers B, Hawkins S, Ravenscroft M, Schulz D (1989) Ullmann’s encyclopedia of industrial chemistry, vol A13, 5th edn. VCH-Verlag, Weinheim
Dannenberg S, Kroder M, Dilling W, Cypionka H (1992) Arch Microbiol 158:93
Chanda M, Grinshpun A, O’Driscoll KF, Rempel GL (1984) J Mol Catal 26:267
Gottschalk G, Knackmuss HJ (1993) Angew Chem Int Ed 32:1398
Meunier B, Sorokin A (1997) Acc Chem Res 30:470
Raghavacharya C (1997) Chem Eng World 32:53
Wakamatsu T, Fuerstenau DW (1973) AIME Trans 254:123
Erdinç A (2009) MSc Thesis, Boğaziçi University, İstanbul, Turkey
Lagergren S (1898) Kungliga Svenska Vetenskapsakademiens, Handlingar 24:1
Ho YS (2010) J Radioanal Nucl Chem 285:403
Gerente C, Lee VKC, Le Cloirec P, Mckay G (2007) Crit Rev Environ Sci Technol 37:41
Doğan M, Alkan M, Türkyılmaz A, Özdemir Y (2004) J Hazard Mater B109:141
Gimbert F, Morin-Crini N, Renault F, Badot PM, Crini G (2008) J Hazard Mater 157:34
Özdemir AB, Turan M, Çelik MS (2003) J Environ Eng 129:709
Langmuir I (1918) J Am Chem Soc 40:1361
Leechart P, Nakbanpote W, Thiravetyan P (2009) J Environ Manag 90:912
Freundlich H (1906) Z Phys Chem 57:385
Al-Duri B (1996) In: McKay G (ed) Use of adsorbents for the removal of pollutants from wastewaters, chap 7. CRC Press, New York
Redlich O, Peterson DL (1959) J Phys Chem 63:1024
Temkin MJ, Pyzhev V (1940) Acta Physicochim 12:217
Fritz W, Schlunder EU (1974) Chem Eng Sci 29:1279
Sabah E, Sağlam H, Kara M, Çelik MS (1997) In: Proceedings of fifth southern hemisphere meeting on mineral technology, Argentina, p 277
Dhar HP, Conway BE, Joshi KM (1973) Electrochim Acta 18:789
Grchev T, Cvetkovska M, Stafilov T, Schultze JW (1991) Electrochim Acta 36:1315
Frumkin AN, Damaskin BB (1964) In: Bockris JOM, Conway BE (eds) Modern aspects of electrochemistry, vol 3. Butterworths, London
Quan C, Khoe G, Bagster D (2001) Water Res 35:478
Sabah E (1998) PhD Thesis, Osmangazi University, Eskişehir, Turkey
Kara M, Yüzer H, Sabah E, Çelik MS (2003) Water Res 37:224
Krishna BS, Murty DSR, Prakash BSJ (2000) J Colloid Interface Sci 229:230
Çelik MS, Yoon RH (1991) Langmuir 7:79
Xin H, Nai-yun G, Qiao-li Z (2007) J Environ Sci 19:1287
Eren E, Afsin B (2008) J Hazard Mater 151:682
Hermosin MC, Martin P, Cornejo J (1993) Environ Sci Technol 27:2606
Çelik MS, Somasundaran P (1988) J Colloid Interface Sci 122:163
Gülgönül İ (2004) PhD Thesis, Istanbul Technical University, Istanbul, Turkey
Takagi S, Eguchi M, Tryk DA, Inoue H (2006) J Photochem Photobiol C 7:104
Ukrainczyk L, Chibwe M, Pinnavaia TJ, Boyd SA (1995) Environ Sci Technol 29:439
Erkan İ (2008) MSc thesis, Karadeniz Technical University, Trabzon, Turkey
Polat M, Gül A (2000) Dyes Pigment 45:195
Kavran G, Akkuş H, Gül A, Erim FB (2002) J Sep Sci 25:514
Sabah E, Çelik MS (2002) Sep Sci Technol 37:3081
Wang S, Li H, Xu L (2006) J Colloid Interface Sci 295:71
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This work was supported by the Research Fund of the Technical University of Istanbul.
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Sevim, A.M., Hojiyev, R., Gül, A. et al. Preparation of novel heterogeneous catalysts by adsorption of a cationic tetrapyrrole on to bentonite: equilibrium, kinetics, and thermodynamics. Monatsh Chem 143, 385–400 (2012). https://doi.org/10.1007/s00706-011-0599-y
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DOI: https://doi.org/10.1007/s00706-011-0599-y