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Construction of a porous Na–Cd mixed metal–organic framework based on biphenyl-4,4′-dicarboxylate and benzotriazole

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Abstract

A novel mixed metal–organic framework, 2H3O·[NaCd3(C14H8O4)3(C6H4N3)3]·5.5H2O, has been synthesized under solvothermal conditions and characterized by single-crystal X-ray structure determination, IR spectroscopy, elemental analysis, TGA, and powder X-ray diffraction. Crystal structure analysis shows that the complex is a 3D framework with hexagonal channels accommodating guest water molecules. Furthermore, the photoluminescence properties and nitrogen gas adsorption of this complex were investigated. The complex exhibits strong photoluminescence emission, and its open cavities possess nitrogen adsorptive ability.

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Acknowledgments

This work was financially supported by Guangdong Provincial Science and Technology Bureau (Grant 2008B010600009), and NSFC (grant nos. 20971047 and U0734005).

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Authors and Affiliations

  1. School of Chemistry and Environment, South China Normal University, Guangzhou, 510006, People’s Republic of China

    Zhiqiang Wei, Shantang Yue, Ning Wang & Wenjing Liu

  2. Department of Chemistry, Jinan University, Guangzhou, 510632, People’s Republic of China

    Yingliang Liu

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  1. Zhiqiang Wei
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  2. Shantang Yue
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  3. Ning Wang
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  4. Wenjing Liu
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  5. Yingliang Liu
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Correspondence to Shantang Yue.

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Wei, Z., Yue, S., Wang, N. et al. Construction of a porous Na–Cd mixed metal–organic framework based on biphenyl-4,4′-dicarboxylate and benzotriazole. Monatsh Chem 143, 421–425 (2012). https://doi.org/10.1007/s00706-011-0592-5

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  • DOI: https://doi.org/10.1007/s00706-011-0592-5

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