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Synthesis and characterization of peroxo complexes of uranium(VI) with some Mannich base ligands

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Abstract

Uranium(VI) peroxo complexes of composition [UO(O2)L–L(NO3)2], where L–L are the Mannich base ligands morpholinobenzyl urea, piperidinobenzyl urea, morpholinobenzyl thiourea, piperidinobenzyl thiourea, morpholinomethyl thiourea, piperidinomethyl thiourea, or morpholinomethyl urea, are reported. The synthesized complexes were characterized by use of a variety of physicochemical techniques, viz. elemental analysis, molar conductivity, magnetic susceptibility measurements, IR, electronic, mass, 1H NMR, and 13C NMR spectroscopy, and TGA/DTA studies. These studies revealed that the complexes are both non-electrolytic and diamagnetic in nature. The ligands are bound to the metal in a bidentate mode through carbonyl oxygen or thiocarbonyl sulfur and the ring nitrogen. Mass spectra confirm the molecular mass of the complexes. The antifungal activity of the complexes is greater than that of the corresponding free ligands.

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References

  1. Mimoun H, de Roch IS, Sajus L (1970) Tetrahedron 26:37

    Article  CAS  Google Scholar 

  2. Miccigrosso DA, Jacobson SE, Apgar PA, Mares F (1978) J Am Chem Soc 100:7063

    Article  Google Scholar 

  3. Jacobson SE, Miccigrosso DA, Mares F (1979) J Org Chem 44:921

    Article  CAS  Google Scholar 

  4. Katsuki T, Sharpless KB (1980) J Am Chem Soc 102:5974

    Article  CAS  Google Scholar 

  5. Rossiter BE, Katsuki T, Sharpless KB (1981) J Am Chem Soc 103:464

    Article  CAS  Google Scholar 

  6. Olah GA, Welch J (1978) J Org Chem 43:2830

    Article  CAS  Google Scholar 

  7. Westland AD, Haque F, Bouchard JM (1980) Inorg Chem 19:2255

    Article  CAS  Google Scholar 

  8. Mimoun H (1980) J Mol Catal 7:1

    Article  CAS  Google Scholar 

  9. Westland AD, Tarafder MTH (1982) Inorg Chem 21:3228

    Article  CAS  Google Scholar 

  10. Tarafder MTH, Khan AR (1987) Polyhedron 6:275

    Article  CAS  Google Scholar 

  11. Saidul Islam M, Masir Uddin M (1992) Polyhedron 11:2913

    Article  Google Scholar 

  12. Tarafder MTH, Bhattacharjee P, Sarkar AK (1992) Polyhedron 11:795

    Article  CAS  Google Scholar 

  13. Tarafder MTH, Ahmed A (1986) Indian J Chem 25(A):729

    Google Scholar 

  14. Dengel AC, Griffith WP (1989) Polyhedron 8:1371

    Article  CAS  Google Scholar 

  15. Islam MS, Uddin MM (1992) Synth React Inorg Met Org Chem 22:893

    Article  CAS  Google Scholar 

  16. Butler A, Clague MJ, Meister GE (1994) Chem Rev 94:625

    Article  CAS  Google Scholar 

  17. Mimoun H, Mignard M, Brechot P, Saussine L (1986) J Am Chem Soc 108:3711

    Article  CAS  Google Scholar 

  18. Crans DC, Smee JJ, Gaidamauskas E, Yang L (2004) Chem Rev 104:849

    Article  CAS  Google Scholar 

  19. Thompson KH, McNeill JH, Orvig C (1999) Chem Rev 99:2561

    Article  CAS  Google Scholar 

  20. Thompson KH, Orvig C (2000) J Chem Soc Dalton Trans 2885

  21. Haldar AK, Banerjee Subha, Naskar K, Kalita D, Islam Nashreen S, Roy Syamal (2009) Exp Parasitol 122:145

    Article  CAS  Google Scholar 

  22. Saleem Mohd, Sharma Mohita, Sheikh HN, Kalsotra BL (2007) Indian J Chem 46(A):1423

    Google Scholar 

  23. Sharma Mohita, Sheikh HN, Singh PM, Kalsotra BL (2008) J Coord Chem 61:426

    Article  Google Scholar 

  24. Kalita D, Sarmah S, Das SP, Baishya D, Patowary A, Baruah S, Islam Nashreen S (2008) React Funct Polym 68:876

    Article  CAS  Google Scholar 

  25. Sharma Mohita, Saleem Mohd, Singh PM, Sheikh HN, Kalsotra BL (2009) Chin J Chem 27:311

    Article  Google Scholar 

  26. Chiarini M, Gillitt ND, Bunton CA (2002) Langmuir 18:3836

    Article  CAS  Google Scholar 

  27. Bunton CA, Gillitt ND (2002) J Phys Org Chem 15:29

    Article  CAS  Google Scholar 

  28. Bandyopadhyay R, Biswas S, Guha S, Mukherjee AK, Bhattacharya R (1999) Chem Commun 1627

  29. Bortolini OS, Compestrini SFD, Furia FD, Modena G (1987) J Org Chem 52:5467

    Article  CAS  Google Scholar 

  30. Bailey AJ, Griffith WP, Parkin BC (1995) J Chem Soc Dalton Trans 1833

  31. Reynolds MS, Morandi SJ, Raebiger JW, Melican SP, Smith SPE (1994) Inorg Chem 33:4977

    Article  CAS  Google Scholar 

  32. Deubel DV, Sundermeyer J, Frenking G (2000) J Org Chem 65:2996

    Article  Google Scholar 

  33. Wahl G, Kleinhenz D, Schorm A, Sundermeyer J, Stowasser R, Rummey C, Bringmann G, Fichert C, Kifer W (1999) Chem Eur J 5:3237

    Article  CAS  Google Scholar 

  34. Cross J, Newman PD, Peacock RD, Stiriling D (1999) J Mol Catal A Chem 144:273

    Article  CAS  Google Scholar 

  35. Deubel DV, Sundermeyer J, Frenking G (2000) J Am Chem Soc 122:10101

    Article  CAS  Google Scholar 

  36. Wang XY, Shi HC, Xu SY (2003) J Mol Catal A Chem 206:213

    Article  CAS  Google Scholar 

  37. Westland AD, Tarafder MTH (1981) Inorg Chem 20:3992

    Article  CAS  Google Scholar 

  38. Islam Saidul M, Begum Motahera, Roy Nath Harandra, Pal SC, Sayenuddin Ahmed (1997) Synth React Inorg Met Org Chem 27:17

    Article  Google Scholar 

  39. Abdel Latif SA (2001) Synth React Inorg Met Org Nano Met Chem 31:1355

    Article  CAS  Google Scholar 

  40. Keramidas AD, Rikkou MP, Drouza C, Raptopoulou CP, Terzis A, Pashalidas I (2002) J Radiochem Acta 90:549

    Article  CAS  Google Scholar 

  41. Raman N, Ravichandran S (2004) Polish J Chem 78:2005

    CAS  Google Scholar 

  42. Raman N, Ravichandran S (2003) Asian J Chem 15:1848

    CAS  Google Scholar 

  43. Haidue L, Silverstru C (1990) Coord Chem Rev 99:253

    Article  Google Scholar 

  44. Cleare MJ (1974) Coord Chem Rev 12:349

    Article  CAS  Google Scholar 

  45. Singh B, Singh RN, Aggarwal RC (1985) Polyhedron 4:401

    Article  CAS  Google Scholar 

  46. Mishra AP, Srivastavan SK (1994) J Indian Counc Chem 10:2

    Google Scholar 

  47. Raman N, Esthar S, Thangaraja C (2004) J Chem Sci 116:209

    Article  CAS  Google Scholar 

  48. Chowdhury Didarul A, Uddin Mohammed N, Sarker MD, Akter H (2008) Chiang Mai J Sci 35:483

    Google Scholar 

  49. Djordjevic C, Vuletic N, Jacobs BA (1997) E Sin Inorg Chem 36:1798

    CAS  Google Scholar 

  50. Sheikh HN, Hussain A, Kalsotra BL (2006) Russ J Inorg Chem 51:724

    Article  Google Scholar 

  51. Gatehouse BM, Livingstone SE, Nyholm RS (1957) J Chem Soc 4222

  52. Curtis NF, Curtis YM (1965) Inorg Chem 4:804

    Article  CAS  Google Scholar 

  53. Nakamoto K (1970) Infrared spectra of inorganic and coordination compounds. Wiley, New York

    Google Scholar 

  54. Thakur Ganesh A, Athlekar Shrikant V, Dharwadker Sanjiv R, Shaikh Manzoor M (2007) Acta Pol Pharma Drug Res 64:9

    CAS  Google Scholar 

  55. Dharmaraj N, Viswanathamorthi P, Natarajan K (2001) Trans Met Chem 26:105

    Article  CAS  Google Scholar 

  56. Mishra L, Singh VK (1999) Indian J Chem A 32:446

    Google Scholar 

  57. Thimmaiah KW, Lloyel WD, Chandrappa GT (1985) Inorg Chim Acta 106:81

    Article  CAS  Google Scholar 

  58. Vogel AI (1978) Quantitative inorganic analysis, 4th edn. ELBS/Longman, London, p 487

    Google Scholar 

  59. Chaudhuri MK, Ghosh SK, Islam NS (1985) Inorg Chem 24:2706

    Article  CAS  Google Scholar 

  60. Weaver WI, Simons JK, Baldwin WE (1944) J Am Chem Soc 66(2):222

    Article  CAS  Google Scholar 

  61. Tarafder MTH, Anwarul Islam AAM (1989) Polyhedron 8:109

    Article  CAS  Google Scholar 

  62. Vincent JH (1947) Nature 15:850

    Article  Google Scholar 

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Authors and Affiliations

  1. Department of Chemistry, University of Jammu, Jammu, 1800 06, India

    Balgar Singh, Simpy Mahajan, Haq N. Sheikh, Mohita Sharma & Bansi L. Kalsotra

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  1. Balgar Singh
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  2. Simpy Mahajan
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  3. Haq N. Sheikh
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  4. Mohita Sharma
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  5. Bansi L. Kalsotra
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Correspondence to Haq N. Sheikh.

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Singh, B., Mahajan, S., Sheikh, H.N. et al. Synthesis and characterization of peroxo complexes of uranium(VI) with some Mannich base ligands. Monatsh Chem 143, 91–99 (2012). https://doi.org/10.1007/s00706-011-0587-2

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  • DOI: https://doi.org/10.1007/s00706-011-0587-2

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