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ESI–IT–MSn and DFT calculation for electron affinities of bimetallic oxovanadium complexes

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Abstract

The MSn spectra of three bimetallic oxovanadium complexes were obtained using an ion trap. The fragmentation pathways were elucidated. Common features and major differences between ESI–QTOF–MS/MS and ESI–IT–MSn spectra were compared. Electron affinities of several radical molecular anions were calculated by DFT and these could be used as an indicator of the ions’ stability.

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Acknowledgements

The authors thank Prof. Liuzhu Gong of the University of Science and Technology of China for providing the samples of bimetallic oxovanadium complexes. And we are also grateful to a referee for his valuable comments.

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Authors and Affiliations

  1. Chengdu Institute of Biology, Chinese Academy of Sciences, Chengdu, 610041, China

    Xia-Li Liao, Chun Wang, Zhi-Jun Wu, Dong-Mei Fang & Guo-Lin Zhang

  2. Graduate School of Chinese Academy of Sciences, Beijing, 100039, China

    Xia-Li Liao

  3. Key Laboratory of Asymmetric Synthesis and Chirotechnology of Sichuan Province and Union Laboratory of Asymmetric Synthesis, Chengdu Institute of Organic Chemistry, Chinese Academy of Sciences, Chengdu, 610041, China

    Xiao-Ying Xu

  4. Department of Chemistry, University of Science and Technology of China, Hefei, 230026, China

    Shi-Wei Luo

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  1. Xia-Li Liao
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  2. Xiao-Ying Xu
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Correspondence to Zhi-Jun Wu or Shi-Wei Luo.

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Liao, XL., Xu, XY., Wang, C. et al. ESI–IT–MSn and DFT calculation for electron affinities of bimetallic oxovanadium complexes. Monatsh Chem 142, 1105–1109 (2011). https://doi.org/10.1007/s00706-011-0580-9

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  • DOI: https://doi.org/10.1007/s00706-011-0580-9

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