Abstract
The intermetallic zinc compounds La3Pd4Zn4 and La3Pt4Zn4 were synthesized by induction melting of the elements in sealed tantalum tubes. The structures were refined from X-ray single-crystal diffractometer data: Gd3Cu4Ge4 type, Immm, a = 1,440.7(5), b = 743.6(2), c = 419.5(2) pm, wR 2 = 0.0511, 353 F 2 for La3Pd4Zn4; and a = 1,439.9(2), b = 748.1(1), c = 415.66(6) pm, wR 2 = 0.0558, 471 F 2 for La3Pt4Zn4 with 23 variables per refinement. The palladium (platinum) and zinc atoms build up a three-dimensional polyanionic [Pd4Zn4] (260–281 pm Pd–Zn) and [Pt4Zn4] (260–279 pm Pt–Zn) network in which the lanthanum atoms fill cavities of CN 14 (6 Pd/Pt + 8 Zn for La1) and CN 12 (6 Pd/Pt + 6 Zn for La2), respectively. The copper position of the Gd3Cu4Ge4 type is occupied by zinc and the two crystallographically independent germanium sites by palladium (platinum), a new coloring pattern for this structure type. Within the [Pd4Zn4] and [Pt4Zn4] the Pd2 and Pt2 atoms form Pd2–Pd2 (291 pm) and Pt2–Pt2 (296 pm) dumbbells. The structures of La3Pd4Zn4 and La3Pt4Zn4 are discussed with respect to the prototype Gd3Cu4Ge4 and the Zintl phase Sr3Li4Sb4. Temperature-dependent magnetic susceptibility measurements indicate diamagnetism for La3Pt4Zn4 and Pauli paramagnetism for La3Pd4Zn4.
Graphical abstract
Similar content being viewed by others
References
Gschneidner KA Jr, Eyring L, Bünzli J-CG, Pecharsky VK (1978-2011) Handbook on the Physics and Chemistry of Rare Earths. Elsevier, Amsterdam, Volumes 1–41
Rodewald UC, Chevalier B, Pöttgen R (2007) J Solid State Chem 180:1720
Tappe F, Pöttgen R (2011) Rev Inorg Chem (in press)
Hermes W, Al Alam AF, Matar SF, Pöttgen R (2008) Solid State Sci 10:1895
Mishra T, Pöttgen R (2011) Intermetallics 19:947
Mishra T, Pöttgen R (2011) Z Naturforsch 66b:671
Makaryk OYa, Dmytriv GS, Kevorkov DG, Pavlyuk VV (2001) J Alloys Compd 317–318:448
Pavlyuk V, Prochwicz W, Solokha P, Zelinska O, Marciniak B, Różycka-Sokołowska E (2006) J Alloys Compd 407:226
De Negri S, Solokha P, Saccone A, Pavlyuk V (2008) Intermetallics 16:168
Contardi V, Zanicchi G, Marazza R, Ferro R (1983) J Less-Common Met 90:L25
Nasch T, Jeitschko W, Rodewald UC (1997) Z Naturforsch 52b:1023
Gross N, Nasch T, Jeitschko W (2001) J Solid State Chem 161:288
Zelinska OYa, Pavlyuk VV, Zelinskiy AV, Davydov VM (2002) J Alloys Compd 343:132
Gross N, Block G, Jeitschko W (2002) Chem Mater 14:2725
Mishra R, Hermes W, Rodewald UC, Hoffmann R-D, Pöttgen R (2008) Z Anorg Allg Chem 634:470
Eyert V, Scheidt E-W, Scherer W, Hermes W, Pöttgen R (2008) Phys Rev B 78:214420
Mishra R, Hermes W, Pöttgen R (2007) Z Naturforsch 62b:1581
Dhar SK, Kulkarni R, Hidaka H, Toda Y, Kotegawa H, Kobayashi TC, Manfrinetti P, Provino A (2009) J Phys Condens Matter 21:156001
Dhar SK, Kulkarni R, Manfrinetti P, Pani M, Yonezawa Y, Aoki Y (2007) Phys Rev B 76:054411
Mishra T, Hermes W, Harmening T, Eul M, Pöttgen R (2009) J Solid State Chem 182:2417
Hermes W, Harmening T, Pöttgen R (2009) Chem Mater 21:3325
Rieger W (1970) Monathsh Chem 101:449
Sheldrick GM (1997) SHELXS-97, Program for the solution of crystal structures, University of Göttingen; (1990) Acta Crystallogr A46:467
Sheldrick GM (1997) SHELXL-97, Program for Crystal Structure Refinement, University of Göttingen; (2008) Acta Crystallogr A64:112
Villars P, Cenzual K (2010) Pearson’s crystal data: crystal structure database for inorganic compounds, release 2009/10, ASM International®. Materials Park, Ohio
Miller GJ (1998) Eur J Inorg Chem 523
Gelato LM, Parthé E (1987) J Appl Crystallogr 20:139
Parthé E, Gelato LM (1984) Acta Crystallogr 40A:69
Emsley J (1999) The elements. Oxford University Press, Oxford
Niepmann D, Prots’ YuM, Pöttgen R, Jeitschko W (2000) J Solid State Chem 154:329
Donohue J (1974) The structures of the elements. Wiley, New York
Liebrich O, Schäfer H, Weiss A (1970) Z Naturforsch 25b:650
Monconduit L, Belin C (1999) Acta Crystallogr C55:1199
Pöttgen R, Gulden Th, Simon A (1999) GIT Labor-Fachz 43:133
Kußmann D, Hoffmann R-D, Pöttgen R (1998) Z Anorg Allg Chem 624:1727
Yvon K, Jeitschko W, Parthé E (1977) J Appl Crystallogr 10:73
Acknowledgments
We thank Dipl.-Ing. U. Ch. Rodewald for the intensity data collections. This work was financially supported by the Deutsche Forschungsgemeinschaft. T.M. is indebted to the Forschungsschule Molecules and Materials–A Common Design Principle for a PhD stipend.
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Mishra, T., Schwickert, C. & Pöttgen, R. La3Pd4Zn4 and La3Pt4Zn4 with a different coloring of the Gd3Cu4Ge4-type structure. Monatsh Chem 142, 973–978 (2011). https://doi.org/10.1007/s00706-011-0569-4
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s00706-011-0569-4