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First Lewis acid catalyzed [4+2] cycloaddition reaction of 1,3,3-trimethyl-2-vinyl-1-cyclohexene with chromones: a new entry to analogues of the puupehenone group of marine diterpenoids and kampanols

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Abstract

A rapid assembly of the tetracyclic core of marine diterpenoids related to puupehenone and kampanols featuring a Lewis acid catalyzed [4+2] cycloaddition reaction of 1,3,3-trimethyl-2-vinyl-1-cyclohexene and chromone dienophiles is described.

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Authors and Affiliations

  1. Department of Chemistry, University of Mumbai, Vidyanagari, Santacruz (East), Mumbai, 400 098, India

    Rajesh M. Kamble & M. M. V. Ramana

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  1. Rajesh M. Kamble
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  2. M. M. V. Ramana
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Correspondence to M. M. V. Ramana.

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Kamble, R.M., Ramana, M.M.V. First Lewis acid catalyzed [4+2] cycloaddition reaction of 1,3,3-trimethyl-2-vinyl-1-cyclohexene with chromones: a new entry to analogues of the puupehenone group of marine diterpenoids and kampanols. Monatsh Chem 142, 501–506 (2011). https://doi.org/10.1007/s00706-011-0480-z

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