Skip to main content
SpringerLink
Log in

A combined extraction and DFT study on the complexation of the silver cation with dibenzo-18-crown-6

  • Original Paper
  • Published:
Monatshefte für Chemie - Chemical Monthly Aims and scope Submit manuscript

Abstract

Extraction experiments in the two-phase water/nitrobenzene system and γ-activity measurements were used to determine the stability constant of the dibenzo-18-crown-6·Ag+ complex species in nitrobenzene saturated with water. Furthermore, the structure of the resulting complex was derived by means of theoretical calculations at the density functional level.

Graphical abstract

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Scheme 1
Fig. 1
Fig. 2

Similar content being viewed by others

References

  1. Pedersen CJ (1967) J Am Chem Soc 89:2495

    Article  CAS  Google Scholar 

  2. Pedersen CJ (1967) J Am Chem Soc 89:7017

    Article  CAS  Google Scholar 

  3. Kolthoff IM (1979) Anal Chem 51:1R

    Article  CAS  Google Scholar 

  4. Makrlík E, Vaňura P (2006) Monatsh Chem 137:157

    Article  Google Scholar 

  5. Makrlík E, Vaňura P (2006) Monatsh Chem 137:1185

    Article  Google Scholar 

  6. Dybal J, Makrlík E, Vaňura P (2007) Monatsh Chem 138:541

    Article  CAS  Google Scholar 

  7. Kříž J, Dybal J, Makrlík E, Budka J, Vaňura P (2007) Monatsh Chem 138:735

    Article  Google Scholar 

  8. Dybal J, Makrlík E, Vaňura P, Selucký P (2007) Monatsh Chem 138:1239

    Article  CAS  Google Scholar 

  9. Dybal J, Makrlík E, Vaňura P, Budka J (2008) Monatsh Chem 139:1175

    Article  CAS  Google Scholar 

  10. Dybal J, Makrlík E, Budka J, Vaňura P (2008) Monatsh Chem 139:1353

    Article  CAS  Google Scholar 

  11. Makrlík E, Dybal J, Vaňura P (2009) Monatsh Chem 140:29

    Article  Google Scholar 

  12. Makrlík E, Dybal J, Budka J, Vaňura P (2009) Monatsh Chem 140:1155

    Article  Google Scholar 

  13. Makrlík E, Čajan M, Budka J, Vaňura P (2011) Monatsh Chem 142 (in press). doi:10.1007/s00706-010-0408-z

  14. Makrlík E, Vaňura P, Budka J (2009) Monatsh Chem 140:583

    Article  Google Scholar 

  15. Toman P, Makrlík E, Vaňura P, Kašička V, Rathore R (2010) Monatsh Chem 141:737

    Article  CAS  Google Scholar 

  16. Rais J (1971) Collect Czech Chem Commun 36:3253

    CAS  Google Scholar 

  17. Makrlík E, Božek F (1998) Polish J Chem 72:949

    Google Scholar 

  18. Makrlík E, Hálová J, Kyrš M (1984) Collect Czech Chem Commun 49:39

    Google Scholar 

  19. Makrlík E, Vaňura P (1996) J Radioanal Nucl Chem 214:339

    Article  Google Scholar 

  20. Daňková M, Makrlík E, Vaňura P (1997) J Radioanal Nucl Chem 221:251

    Article  Google Scholar 

  21. Makrlík E, Vaňura P, Daňková M (1999) J Radioanal Nucl Chem 240:579

    Article  Google Scholar 

  22. Makrlík E, Vaňura P (2006) Z Phys Chem 220:1125

    Google Scholar 

  23. Frisch MJ, Trucks GW, Schlegel HB, Scuseria GE, Robb MA, Cheeseman JR, Montgomery Jr JA, Vreven T, Kudin KN, Burant JC, Millam JM, Iyengar SS, Tomasi J, Barone V, Mennucci B, Cossi M, Scalmani G, Rega N, Petersson GA, Nakatsuji H, Hada M, Ehara M, Toyota K, Fukuda R, Hasegawa J, Ishida M, Nakajima T, Honda Y, Kitao O, Nakai H, Klene M, Li X, Knox JE, Hratchian HP, Cross JB, Bakken V, Adamo C, Jaramillo J, Gomperts R, Stratmann RE, Yazyev O, Austin AJ, Cammi R, Pomelli C, Ochterski JW, Ayala PY, Morokuma K, Voth GA, Salvador P, Dannenberg JJ, Zakrzewski VG, Dapprich S, Daniels AD, Strain MC, Farkas O, Malick DK, Rabuck AD, Raghavachari K, Foresman JB, Ortiz JV, Cui Q, Baboul AG, Clifford S, Cioslowski J, Stefanov BB, Liu G, Liashenko A, Piskorz P, Komaromi I, Martin RL, Fox DJ, Keith T, Al-Laham MA, Peng CY, Nanayakkara A, Challacombe M, Gill PMW, Johnson B, Chen W, Wong MW, Gonzalez C, Pople JA (2004) Gaussian 03, Revision C. 02, Gaussian, Wallingford

  24. Kříž J, Dybal J, Makrlík E (2006) Biopolymers 82:536

    Article  Google Scholar 

  25. Kříž J, Dybal J, Makrlík E, Vaňura P, Lang J (2007) Supramol Chem 19:419

    Article  Google Scholar 

  26. Kříž J, Dybal J, Makrlík E, Vaňura P (2008) Supramol Chem 20:387

    Article  Google Scholar 

  27. Kříž J, Dybal J, Makrlík E, Budka J, Vaňura P (2008) Supramol Chem 20:487

    Article  Google Scholar 

  28. Kříž J, Dybal J, Makrlík E, Budka J (2008) J Phys Chem A 112:10236

    Article  Google Scholar 

  29. Kříž J, Dybal J, Makrlík E, Budka J, Vaňura P (2009) J Phys Chem A 113:5896

    Article  Google Scholar 

  30. Hawthorne MF, Young DC, Andrews TD, Howe DV, Pilling RL, Pitts AD, Reintjes M, Warren LF, Wegner PA (1968) J Am Chem Soc 90:879

    Article  CAS  Google Scholar 

  31. Makrlík E, Vaňura P (1985) Talanta 32:423

    Article  Google Scholar 

  32. Makrlík E (1992) Collect Czech Chem Commun 57:289

    Article  Google Scholar 

Download references

Acknowledgments

This work was supported by the Czech Ministry of Education, Youth, and Sports (projects MSM 4977751303 and MSM 6046137307) and by the Czech Science Foundation (project P205/10/2280). The computer time at the MetaCentrum (project MSM 6383917201), as well as at the Institute of Physics (computer Luna/Apollo), Academy of Sciences of the Czech Republic, is gratefully acknowledged.

Author information

Authors and Affiliations

  1. Faculty of Applied Sciences, University of West Bohemia, Pilsen, Czech Republic

    Emanuel Makrlík

  2. Institute of Macromolecular Chemistry, Academy of Sciences of the Czech Republic, Prague, Czech Republic

    Petr Toman

  3. Department of Analytical Chemistry, Institute of Chemical Technology, Prague, Czech Republic

    Petr Vaňura

Authors
  1. Emanuel Makrlík
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Petr Toman
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Petr Vaňura
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Emanuel Makrlík.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Makrlík, E., Toman, P. & Vaňura, P. A combined extraction and DFT study on the complexation of the silver cation with dibenzo-18-crown-6. Monatsh Chem 142, 137–140 (2011). https://doi.org/10.1007/s00706-010-0432-z

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s00706-010-0432-z

Keywords

Search

Navigation