Skip to main content
Log in

Study of polyaniline conducting/electroactive polymer as sensor for some agricultural phosphorus pesticides

  • Original Paper
  • Published:
Monatshefte für Chemie - Chemical Monthly Aims and scope Submit manuscript

Abstract

Due to their wide applications as insecticides, pesticides, chemical warfare agents, etc., detection of organophosphorus compounds is of great importance. This paper deals with application of polyaniline conducting polymer (PANi) as a sensor material for detection of some agricultural organophosphorus compounds that are commonly used as insecticides and pesticides. The compounds employed in this investigation are dichlorvos, trichlorophon, and chlorpyrifos. The effects of some important parameters such as concentration, thickness of the polymer film, etc., on electrical conductivity and conductivity stability for these compounds have also been investigated. In situ electrical conductivity measurements were performed using a standard direct-current (DC) four-point probe technique. It was found that adsorption and desorption of these compounds on PANi film cause measurable change in the resistance of conducting polymers.

Graphical Abstract

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9
Fig. 10
Scheme 1

Similar content being viewed by others

References

  1. Feldman BJ, Burgmayer P, Marray RW (1985) J Am Chem Soc 107:872

    Article  CAS  Google Scholar 

  2. Parneix JP, Kadiri ME (1987) In: Kuzamany H, Mehring M, Roth S (eds) Electronic properties of conjugated polymers, Spring series in solid state sciences, vol 76, Springer, Berlin, p 23

  3. Chandler GK, Pletcher D (1985) The electrochemistry of conducting polymers. Spec Period Rep. Electrochem vol 10, R Soc Chem, London, p 117

  4. Li N, Lee Y, Ong LH (1992) J Appl Electrochem 22:512

    Article  CAS  Google Scholar 

  5. Trinidad F, Montmayer MC, Fatas E (1991) J Electrochem Soc 138:3186

    Article  CAS  Google Scholar 

  6. Carey WP, Beebe KR, Kouwalski BR, Illman DL, Hirschfeld T (1986) Anal Chem 58:149

    Article  CAS  Google Scholar 

  7. Muller R, Lange E (1986) Actuators 9:39

    Article  Google Scholar 

  8. Amrani MEH, Payne PA (1999) IEE Proc Sci Meas Technol 2:95

    Article  Google Scholar 

  9. Carey WP, Beebe KR, Kowaalski BR (1987) Anal Chem 59:1529

    Article  CAS  Google Scholar 

  10. Gardner JW, Bartlet PN (1995) Sens Actuators A 51:57

    Article  Google Scholar 

  11. Hosseini SH, Noor P (2005) Iran Polym J 14:55

    CAS  Google Scholar 

  12. Wang J (2002) Synth Met 132:49

    Article  CAS  Google Scholar 

  13. Wang J (2002) Synth Met 132:53

    Article  CAS  Google Scholar 

  14. Colaneri F, Shacklett LW (1992) IEEE Trans Instrum Meas 2:291

    Article  Google Scholar 

  15. Dhawan SK, Trivedi DC (1991) J Electromagn Compat 4:1

    Google Scholar 

  16. Thostenson ET, Chou TW (1999) Fundam Appl Compos A 30:1055

    Article  Google Scholar 

  17. Chung YC, Kim BW, Park DC (1999) J Korea Electromagn Eng Soc 10:440

    Google Scholar 

  18. Kuo CT, Kuo HH, Chen SA, Hwang GW (1998) Synth Met 93:155

    Article  CAS  Google Scholar 

  19. Boyel A, Geneis EM, Lapkowaski M (1989) Synth Met 28:769

    Article  Google Scholar 

  20. Agbor NE, Petty MC, Monkman AP (1995) Sens Actuators B 28:173

    Article  Google Scholar 

  21. Athawale AA, Kulkarni MV (2000) Sens Actuators B 67:173

    Article  Google Scholar 

  22. Sukeerthi S, Contractor AQ (1994) Indian J Chem Sect A 33:565

    Google Scholar 

  23. Hatfield V, Neaves P, Hicks PJ, Persaud K, Travers P (1994) Sens Actuators B 18/19:221

    Article  Google Scholar 

  24. Hosseini SH, Entezami AA (2001) Polym Adv Sci Technol 12:482

    Article  CAS  Google Scholar 

  25. Hosseini SH, Entezami AA (2003) J Appl Polym Sci 90:49

    Article  CAS  Google Scholar 

  26. Ngeh-Ngwainbi J, Foley PH, Kuan SS, Guilbault GG (1986) J Am Chem Soc 108:515

    Article  Google Scholar 

  27. Nieuwenhuizen MS, Harteveld JLN (1994) Talanta 41:461

    Article  CAS  Google Scholar 

  28. Kuo CT, Chen CH (1999) Synth Met 99:163

    Article  CAS  Google Scholar 

  29. Bellocci M (2002) SENSPOL Newsl 8:6

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Seyed Hossein Hosseini.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Hosseini, S.H., Khalkhali, R.A. & Noor, P. Study of polyaniline conducting/electroactive polymer as sensor for some agricultural phosphorus pesticides. Monatsh Chem 141, 1049–1053 (2010). https://doi.org/10.1007/s00706-010-0374-5

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s00706-010-0374-5

Keywords

Navigation