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The scale-up of material microstructuring: from scanning probes to self-assembly

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Abstract

The behaviour of materials is governed by their microstructures, whether they are naturally occurring or artificially designed. Engineered microstructures lead to materials with new and useful functions, but their real-world application requires scalable microstructuring methods for production. This review discusses several principles of fabrication and their scalability. Replication by imprint and multiplexed probes are obvious candidates for scale-up, but they limit the choice of materials. The assembly of interacting particles is a promising, scalable fabrication method. A wide range of materials can be obtained as particles which assemble into regular superstructures, but large-scale structuring at high precision and yield as yet remains a challenge.

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References

  1. Arzt E, Gorb S, Spolenak R (2003) Proc Natl Acad Sci U S A 100:10603

    Article  CAS  Google Scholar 

  2. Shalaev VM, Cai WS, Chettiar UK, Yuan HK, Sarychev AK, Drachev VP, Kildishev AV (2005) Opt Lett 30:3356

    Article  Google Scholar 

  3. Dimitrov AS, Nagayama K (1996) Langmuir 12:1303

    Article  CAS  Google Scholar 

  4. White SR, Sottos NR, Geubelle PH, Moore JS, Kessler MR, Sriram SR, Brown EN, Viswanathan S (2001) Nature 409:794

    Article  CAS  Google Scholar 

  5. del Campo A, Greiner C, Arzt E (2007) Langmuir 23:10235

    Article  CAS  Google Scholar 

  6. Blanco A, Chomski E, Grabtchak S, Ibisate M, John S, Leonard SW, Lopez C, Meseguer F, Miguez H, Mondia JP, Ozin GA, Toader O, van Driel HM (2000) Nature 405:437

    Article  CAS  Google Scholar 

  7. Madou MC (2010) Manufacturing techniques for microfabrication and nanotechnology. CRC, Boca Raton

    Google Scholar 

  8. Michel B, Bernard A, Bietsch A, Delamarche E, Geissler M, Juncker D, Kind H, Renault JP, Rothuizen H, Schmid H, Schmidt-Winkel P, Stutz R, Wolf H (2001) IBM J Res Dev 45:697

    Article  CAS  Google Scholar 

  9. Rolland JP, Maynor BW, Euliss LE, Exner AE, Denison GM, DeSimone JM (2005) J Am Chem Soc 127:10096

    Article  CAS  Google Scholar 

  10. Gates BD, Xu QB, Stewart M, Ryan D, Willson CG, Whitesides GM (2005) Chem Rev 105:1171

    Article  CAS  Google Scholar 

  11. Renesse RL (2005) Optical document security, 3rd edn. Artech, Boston

    Google Scholar 

  12. Moon JH, Ford J, Yang S (2006) Polym Adv Technol 17:83

    Article  CAS  Google Scholar 

  13. Sekula S, Fuchs J, Weg-Remers S, Nagel P, Schuppler S, Fragala J, Theilacker N, Franueb M, Wingren C, Ellmark P, Borrebaeck CAK, Mirkin CA, Fuchs H, Lenhert S (2008) Small 4:1785

    Article  CAS  Google Scholar 

  14. Salaita K, Wang YH, Fragala J, Vega RA, Liu C, Mirkin CA (2006) Angew Chem Int Ed 45:7220

    Article  CAS  Google Scholar 

  15. Pires D, Hedrick JL, De Silva A, Frommer J, Gotsmann B, Wolf H, Despont M, Duerig U, Knoll AW (2010) Science 328:732

    Article  CAS  Google Scholar 

  16. Glotzer SC, Solomon MJ (2007) Nat Mater 6:557

    Article  Google Scholar 

  17. Lindsey JS (1991) New J Chem 15:153

    CAS  Google Scholar 

  18. Shevchenko EV, Talapin DV, Kotov NA, O’Brien S, Murray CB (2006) Nature 439:55

    Article  CAS  Google Scholar 

  19. Velikov KP, Christova CG, Dullens RPA, van Blaaderen A (2002) Science 296:106

    Article  CAS  Google Scholar 

  20. Whitesides GM, Grzybowski B (2002) Science 295:2418

    Article  CAS  Google Scholar 

  21. Murphy MP, Kim S, Sitti M (2009) ACS Appl Mater Interfaces 1:849

    Article  CAS  Google Scholar 

  22. Autumn K, Liang YA, Hsieh ST, Zesch W, Chan WP, Kenny TW, Fearing R, Full RJ (2000) Nature 405:681

    Article  CAS  Google Scholar 

  23. Jeong HE, Lee JK, Kim HN, Moon SH, Suh KY (2009) Proc Natl Acad Sci U S A 106:5639

    Article  CAS  Google Scholar 

  24. Kraus T, Malaquin L, Delamarche E, Schmid H, Spencer ND, Wolf H (2005) Adv Mater 17:2438

    Article  CAS  Google Scholar 

  25. Pinto YY, Le JD, Seeman NC, Musier-Forsyth K, Taton TA, Kiehl RA (2005) Nano Lett 5:2399

    Article  CAS  Google Scholar 

  26. Sharma J, Chhabra R, Liu Y, Ke YG, Yan H (2006) Angew Chem Int Ed 45:730

    Article  CAS  Google Scholar 

  27. Murray CB, Kagan CR, Bawendi MG (2000) Ann Rev Mat Sci 30:545

    Article  CAS  Google Scholar 

  28. Glaser J, Carroad PA, Dunkley WL (1980) J Dairy Sci 63:37

    Article  Google Scholar 

  29. Chen Z, O’Brien S (2008) ACS Nano 2:1219

    Article  CAS  Google Scholar 

  30. Laves F (1956) In: Proceedings of theory of alloy phases: a seminar on theory of alloy phases held during the thirty-seventh national metal congress and exposition, Philadelphia, USA, October 15 to 21, 1955, American Society for Metals, p 125

  31. Solomon T, Solomon MJ (2006) J Chem Phys 124:134905

    Article  Google Scholar 

  32. Weitz DA, Huang JS, Lin MY, Sung J (1985) Phys Rev Lett 54:1416

    Article  CAS  Google Scholar 

  33. Malaquin L, Kraus T, Schmid H, Delamarche E, Wolf H (2007) Langmuir 23:11513

    Article  CAS  Google Scholar 

  34. Heath JR, Kuekes PJ, Snider GS, Williams RS (1998) Science 280:1716

    Article  CAS  Google Scholar 

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Acknowledgments

The author thanks Marleen Kamperman and Eoin Murray for helpful discussions and Eduard Arzt for his continuous support.

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Correspondence to Tobias Kraus.

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Kraus, T. The scale-up of material microstructuring: from scanning probes to self-assembly. Monatsh Chem 141, 1267–1272 (2010). https://doi.org/10.1007/s00706-010-0364-7

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  • DOI: https://doi.org/10.1007/s00706-010-0364-7

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