Skip to main content
SpringerLink
Log in

Synthesis, structural characterization, and magnetic properties of the metallamacrocycle [Fe6(C11H11N2O3)6(C4H9NO)6]

  • Original Paper
  • Published:
Monatshefte für Chemie - Chemical Monthly Aims and scope Submit manuscript

Abstract

The 18-metallacrown-6 metallamacrocycle [Fe6(pmshz)6(C4H9NO)6] has been synthesized by the self-assembly reaction of iron ions with N-substituted salicylhydrazide ligands. Six Fe(III) ions and six deprotonated N-propanoyl-4-methylsalicylhydrazide (H3 pmshz) ligands construct a planar 18-membered ring based on Fe–N–N–Fe linkage. Because of the coordination, the ligand enforces the stereochemistry of the Fe(III) ions as a propeller shape with alternating …ΔΛΔΛ… configurations. There is a strong antiferromagnetic exchange interaction between the paramagnetic iron centers.

Graphical abstract

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Scheme 1
Fig. 2

Similar content being viewed by others

References

  1. Pecoraro VL, Stemmler AJ, Gibbney BR, Bodwin JJ, Wang H, Kampf JW, Barwinski A (1997) In: Karlin KD (ed) Progress in inorganic chemistry, vol 45, Wiley, New York, pp 83–177

  2. Lah MS, Pecoraro VL (1989) J Am Chem Soc 111:7258

    Article  CAS  Google Scholar 

  3. Loi M, Hosseini MW, Jouaiti A, Cian AD, Fischer J (1999) Eur J Inorg Chem P1981

  4. Halper SR, Cohen SM (2004) Angew Chem Int Ed 43:2385

    Article  CAS  Google Scholar 

  5. Su C-Y, Yang X-P, Kang B-S, Mak TCW (2001) Angew Chem Int Ed 40:1725

    Article  CAS  Google Scholar 

  6. Moon M, Kim I, Lah MS (2000) Inorg Chem 39:2710

    Article  CAS  Google Scholar 

  7. Moon D, Song J, Kim BJ, Suh BJ, Lah MS (2004) Inorg Chem 43:8230

    Article  CAS  Google Scholar 

  8. Moon D, Lah MS (2005) Inorg Chem 44:1934

    Article  CAS  Google Scholar 

  9. Mezei G, Baran P, Raptis RG (2004) Angew Chem Int Ed 43:574

    Article  CAS  Google Scholar 

  10. Slone RV, Benkstein KD, Be′langer S, Hupp JT, Guzei IA, Rheingold AL (1998) Coord Chem Rev 171:221

    CAS  Google Scholar 

  11. Bodwin JJ, Cutland AD, Malkani RG, Pecoraro VL (2001) Coord Chem Rev P216

  12. Willermann M, Mulcahy C, Sigel RKO, Cerdà MM, Freisinger E, Miguel PJS, Roitzsch M, Lippert B (2006) Inorg Chem 45:2093

    Article  CAS  Google Scholar 

  13. Severin K (2003) Coord Chem Rev 245:3

    Article  CAS  Google Scholar 

  14. Overgaard J, Iversen BB, Palii SP, Timco GA, Gerbeleu NV, Larsen FK (2002) Chem Eur J 8:2775

    Article  CAS  Google Scholar 

  15. Lehaire M-L, Scopelliti R, Severin K (2002) Inorg Chem 41:5466

    Article  CAS  Google Scholar 

  16. Su C-Y, Cai Y-P, Chen C-L, Smith MD, Kaim W, Loye H-C (2003) J Am Chem Soc 125:8595

    Article  CAS  Google Scholar 

  17. Halper SR, Cohen SM (2004) Angew Chem Int Ed 43:23

    Article  Google Scholar 

  18. Hong M, Zhao Y, Su W, Cao R, Fujita M, Zhou Z, Chan ASC (2000) J Am Chem Soc 122:4819

    Article  CAS  Google Scholar 

  19. Gaynor D, Starikova ZA, Ostrovsky S, Hasse W, Nolan KB (2002) Chem Commun P506

  20. Olenyuk B, Whiteford JA, Fechtenkotter A, Stang PJ (1999) Nature 398:796

    Article  CAS  Google Scholar 

  21. Schnebeck R-D, Friesinger E, Glahe F, Lippert B (2000) J Am Chem Soc 122:1381

    Article  CAS  Google Scholar 

  22. Olenyuk B, Levin MD, Whiteford JA, Shield JE, Stang PJ (1999) J Am Chem Soc 121:10434

    Article  CAS  Google Scholar 

  23. Lai S-W, Cheung K-K, Chan MC-W, Che C-M (1998) Angew Chem Int Ed 37:182

    Article  CAS  Google Scholar 

  24. Kwak B, Rhee H, Park S, Lah MS (2000) Polyhedron 19:1985

    Article  CAS  Google Scholar 

  25. Kim I, Kwak B, Lah MS (2001) Inorg Chim Acta 317:12

    Article  CAS  Google Scholar 

  26. Lin S, Liu S-X, Huang J-Q, Lin C-C (2002) J Chem Soc Dalton Trans 1595

  27. Jones LF, Batsanov A, Brechin EK, Collison D, Helliwell M, Mallah T, McInnes EJL, Piligkos S (2002) Angew Chem Int Ed 41:4318

    Article  CAS  Google Scholar 

  28. Tasiopoulos AJ, Vinslava A, Wernsdorfer W, Abboud KA, Christou G (2004) Angew Chem Int Ed 43:2117

    Article  CAS  Google Scholar 

  29. Liu S-X, Lin S, Lin B-Z, Lin C-C, Huang J-Q (2001) Angew Chem Int Ed 40:1084

    Article  CAS  Google Scholar 

  30. Lin S, Liu S-X, Chen Z, Lin B-Z, Gao S (2004) Inorg Chem 43:2222

    Article  CAS  Google Scholar 

  31. Nakamoto K (1986) Infrared and Raman spectra of inorganic and coordination compounds, 4th edn. Wiley, New York

    Google Scholar 

  32. Borrás-Almenar JJ, Clemente-Juan JM, Coronado E, Tsukerblat B (1999) Inorg Chem 38:6081

    Article  Google Scholar 

  33. King P, Clérac R, Wernsdorfer W, Anson CE, Powell AK (2004) Dalton Trans 2670

  34. Telfer SG, Kuroda R, Lefebvre J, Leznoff DB (2006) Inorg Chem 45:4592

    Article  CAS  Google Scholar 

  35. Bruker AXS Inc, SMART APEX (Version 5.628), SAINT+ (Version 6.45), SHELXTL- NT (Version 6.12) (2001) Bruker AXS Inc, Madison, WI, USA

  36. Sheldrick GM (1997) SHELXS97 and SHELXL97. University of Gottingen, Germany

    Google Scholar 

Download references

Acknowledgments

We gratefully acknowledge the Talent Fund of Ningbo Municipal Natural Science Foundation (no. 2008A610051) and K.C. Wong Magna Fund in Ningbo University for financial support of the work.

Author information

Authors and Affiliations

  1. State Key Laboratory Base of Novel Functional Materials and Preparation Science, Faculty of Materials Science and Chemical Engineering, Institute of Solid Materials Chemistry, Ningbo University, Ningbo, 315211, People’s Republic of China

    Ke-Wei Lei, Hai-Mei Feng, Jun-Long Wen & Tian-Pin Shu

Authors
  1. Ke-Wei Lei
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Hai-Mei Feng
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Jun-Long Wen
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Tian-Pin Shu
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Ke-Wei Lei.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Lei, KW., Feng, HM., Wen, JL. et al. Synthesis, structural characterization, and magnetic properties of the metallamacrocycle [Fe6(C11H11N2O3)6(C4H9NO)6]. Monatsh Chem 141, 743–747 (2010). https://doi.org/10.1007/s00706-010-0322-4

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s00706-010-0322-4

Keywords

Search

Navigation