Skip to main content

Advertisement

SpringerLink
Log in

Organo-modified mesoporous silica for sorption of carbon dioxide

  • Original Paper
  • Published:
Monatshefte für Chemie - Chemical Monthly Aims and scope Submit manuscript

Abstract

Organo-modified mesoporous silica SBA-15 has been studied for sorption of carbon dioxide (CO2). The SBA-15 sample was functionalized with a branched chain polymer, polyethylenimine (PEI), of different molecular weights (1,300 and 2,000 g mol−1). Surface modification was carried out by impregnation of silica by PEI or by grafting with (3-chloropropyl)triethoxysilane, followed by substitution of chlorine atoms by PEI ligands. The prepared modified mesoporous materials were characterized by nitrogen adsorption/desorption at 77 K, high-resolution transmission electron microscopy, small-angle X-ray scattering, and thermal methods. Sorption of CO2 was studied by gravimetric method at 303 K. The total amount of sorbed CO2 varied between 0.19–0.67 mmol/g for respective samples. Regeneration of the materials after adsorption was achieved by thermal treatment at 343 K.

Graphical abstract

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8

Similar content being viewed by others

References

  1. Cantarel A, Bloor JMG, Jean-François S (2009) IOP Conf Ser Earth Environ Sci 6:242044

    Article  Google Scholar 

  2. Cox PM, Betts RA, Jones CD, Spall SA, Totterdell IJ (2000) Nature 408:184

    Article  CAS  Google Scholar 

  3. Cramer W, Bondeau A, Woodward FI, Prentice IC, Betts RA, Brovkin V, Cox PM, Fisher V, Foley JA, Friend AD, Kucharik C, Lomas MR, Ramankutty N, Sitch S, Smith B, White A, Young-Molling C (2001) Glob Chang Biol 7:357

    Article  Google Scholar 

  4. Matthews HD, Gillett NP, Stott PA, Zickfeld K (2009) Nature 459:829

    Article  CAS  Google Scholar 

  5. Ledley TS, Sundquist ET, Schwartz SE (1999) Eos Trans AGU 80:453

    Article  Google Scholar 

  6. Xu X, Song Ch, Miller BG, Scaroni AW (2005) Ind Eng Chem Res 44:8133

    Google Scholar 

  7. Xu X, Song C, Andrésen J, Miller BG, Scaroni AW (2003) Microporous Mesoporous Mater 62:29

    Article  CAS  Google Scholar 

  8. Wong S, Bioletti R (2002) Carbon dioxide separation technologies, carbon & energy management alberta research council. Edmonton, Alberta

    Google Scholar 

  9. Veaweb A, Tontiwachwuthikul P, Chakma A (1999) Ind Eng Chem Res 38:3917

    Article  Google Scholar 

  10. Chakma A (1997) Energy Conversat Manage 38:S51

    Article  CAS  Google Scholar 

  11. Leal O, Bolivar C, Ovalles C, Garcia JJ, Espidel Y (1995) Inorg Chim Acta 240:183

    Article  CAS  Google Scholar 

  12. Huang HY, Yang RT, Chinn D, Munson CL (2003) Ind Eng Chem Res 42:2427

    Article  CAS  Google Scholar 

  13. Hiyoshi N, Yogo K, Yashima T (2004) Stud Surf Sci Catal 154:2995

    Article  Google Scholar 

  14. Kim S, Ida J, Guliants VV, Lin JYS (2005) J Phys Chem B 109:6287

    Article  CAS  Google Scholar 

  15. Zeleňák V, Halamová D, Gaberová L, Bloch E, Llewellyn P (2008) Microporous Mesoporous Mater 116:358

    Article  Google Scholar 

  16. Son W, Choi J, Ahn W (2008) Microporous Mesoporous Mater 113:31

    Article  CAS  Google Scholar 

  17. Wang X, Schwartz V, Clark JC, Ma X, Overbury SH, Xu X, Song C (2009) J Phys Chem C 113:7260

    Article  CAS  Google Scholar 

  18. Xu X, Song C, Miler BG, Scaroni AW (2005) Fuel Process Tech 86:1457

    Article  CAS  Google Scholar 

  19. Kumar P, Kim S, Ida J, Guliants VV (2008) Ind Eng Chem Res 47:201

    Article  CAS  Google Scholar 

  20. Sing KSW, Everett DH, Haul RAW, Moscou L, Pierotti RA, Rouquérol J, Siemieniewska T (1985) Pure Appl Chem 57:603

    Article  CAS  Google Scholar 

  21. Yoshitake H, Koiso E, Horie H, Yoshimura H (2005) Microporous Mesoporous Mater 85:183

    Article  CAS  Google Scholar 

  22. Gao B, An F, Liu K (2006) Appl Surf Sci 253:1946

    Article  CAS  Google Scholar 

  23. Xu Q, Dong W, Li H, Li L, Feng S, Xu R (2003) Solid State Sci 5:777

    Article  CAS  Google Scholar 

  24. Zheng F, Tran DN, Busche BJ, Fryxell GE, Addleman RS, Zemanian TS, Aardahl CL (2005) Ind Eng Chem Res 44:3099

    Article  CAS  Google Scholar 

  25. Serna-Guerrero R, Dana E, Sayari A (2008) Ind Eng Chem Res 47:9406

    Article  CAS  Google Scholar 

  26. Knöfel C, Descarpentries J, Benzaouia A, Zeleňák V, Mornet S, Llewyllyn PL, Hornebecq V (2007) Microporous Mesoporous Mater 99:77

    Google Scholar 

  27. Khatri RA, Chuang SSC, Soong A, McMahan G (2005) Ind Eng Chem Res 44:3702

    Article  CAS  Google Scholar 

Download references

Acknowledgments

This work was supported in part by the European Community STREP project “DeSANNS” (no. FP6-SES6-020133), the Slovak Research and Development Agency under contract RPEU-0027-06 (OrNaMat), the VEGA project (no. 1/0119/08) of the Ministry of Education of the Slovak Republic, and grant VVGS PF 14/2009/CH. The ERDF EU (Operational Program “Research and Development” financed through European Regional Development Fund) grant, under contract ITMS 26220120019 (Centre of Excellence of Advanced Materials with Nano, and Submicron, Structure) is also gratefully acknowledged. The authors thank Dr. U. Vainio (DESY/Hasylab, Hamburg, Germany) for assistance at the B1 beamline and Dr. N. Murafa (IIC AS CR, Rez, Czech Republic) for TEM measurements.

Author information

Authors and Affiliations

  1. Department of Inorganic Chemistry, P. J. Šafárik University, Moyzesova 11, Košice, Slovak Republic

    Mária Badaničová & Vladimír Zeleňák

Authors
  1. Mária Badaničová
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Vladimír Zeleňák
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Mária Badaničová.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Badaničová, M., Zeleňák, V. Organo-modified mesoporous silica for sorption of carbon dioxide. Monatsh Chem 141, 677–684 (2010). https://doi.org/10.1007/s00706-010-0304-6

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s00706-010-0304-6

Keywords

Search

Navigation