Skip to main content
SpringerLink
Log in

Solvent extraction of silver trifluoromethanesulfonate from water into nitrobenzene in the presence of silver ionophore IV

  • Original Paper
  • Published:
Monatshefte für Chemie - Chemical Monthly Aims and scope Submit manuscript

Abstract

From extraction experiments in the two-phase water/nitrobenzene system, the stability constant of the silver ionophore IV (i.e., 5,11,17,23-tetra-tert-butyl-25,27-bis[2-(methylthio)ethoxy]calix[4]arene)–Ag+ complex in nitrobenzene saturated with water was determined. Furthermore, the most probable structure of the resulting complex was derived by means of density functional level of theory calculations.

Graphical abstract

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Scheme 1
Fig. 1
Fig. 2

Similar content being viewed by others

References

  1. Böhmer V (1995) Angew Chem Int Ed 34:713

    Article  Google Scholar 

  2. Gutsche CD (1998) Calixarenes revisited. The Royal Society of Chemistry, Cambridge

    Google Scholar 

  3. Arduini A, Pochini A, Reverberi S, Ungaro R (1986) Tetrahedron 42:2089

    Article  CAS  Google Scholar 

  4. Arduini A, Ghidini E, Pochini A, Ungaro R, Andreetti GD, Calestani G, Ugozzoli F (1988) J Incl Phenom 6:119

    Article  CAS  Google Scholar 

  5. Arnaud-Neu F, Collins EM, Deasy M, Ferguson G, Harris SJ, Kaitner B, Lough AJ, McKervey MA, Marques E, Ruhl BL, Schwing-Weill MJ, Seward EM (1989) J Am Chem Soc 111:8681

    Article  CAS  Google Scholar 

  6. Arnaud-Neu F, Barrett G, Harris SJ, Owens M, McKervey MA, Schwing-Weill MJ, Schwinté P (1993) Inorg Chem 32:2644

    Article  CAS  Google Scholar 

  7. Ohto K, Murakami E, Shinohara T, Shiratsuchi K, Inoue K, Iwasaki M (1997) Anal Chim Acta 341:275

    Article  CAS  Google Scholar 

  8. Ye Z, He W, Shi X, Zhu L (2001) J Coord Chem 54:105

    Article  CAS  Google Scholar 

  9. Danil de Namor AF, Chahine S, Kowalska D, Castellano EE, Piro OE (2002) J Am Chem Soc 124:12824

    Article  CAS  Google Scholar 

  10. Marcos PM, Ascenso JR, Segurado MAP, Pereira JLC (2002) J Inclusion Phenom 42:281

    Article  CAS  Google Scholar 

  11. Marcos PM, Félix S, Ascenso JR, Segurado MAP, Pereira JLC, Khazaeli -Parsa P, Hubscher–Bruder V, Arnaud-Neu F (2004) New J Chem 28:748

    Article  CAS  Google Scholar 

  12. Makrlík E, Vaňura P (2006) Monatsh Chem 137:1185

    Article  Google Scholar 

  13. Dybal J, Makrlík E, Vaňura P (2007) Monatsh Chem 138:541

    Article  CAS  Google Scholar 

  14. Kříž J, Dybal J, Makrlík E, Budka J, Vaňura P (2007) Monatsh Chem 138:735

    Article  Google Scholar 

  15. Dybal J, Makrlík E, Vaňura P, Selucký P (2007) Monatsh Chem 138:1239

    Article  CAS  Google Scholar 

  16. Dybal J, Makrlík E, Vaňura P, Budka J (2008) Monatsh Chem 139:1175

    Article  CAS  Google Scholar 

  17. Dybal J, Makrlík E, Budka J, Vaňura P (2008) Monatsh Chem 139:1353

    Article  CAS  Google Scholar 

  18. Makrlík E, Dybal J, Vaňura P (2009) Monatsh Chem 140:29

    Article  Google Scholar 

  19. Makrlík E, Dybal J, Budka J, Vaňura P (2009) Monatsh Chem 140:1155

    Article  Google Scholar 

  20. Malinowska E, Brzózka Z, Kasiura K, Egberink RJM, Reinhoudt DN (1994) Anal Chim Acta 298:245

    Article  CAS  Google Scholar 

  21. Rais J (1971) Collect Czech Chem Commun 36:3253

    CAS  Google Scholar 

  22. Makrlík E, Vaňura P (1985) Talanta 32:423

    Article  Google Scholar 

  23. Makrlík E, Božek F (1998) Polish J Chem 72:949

    Google Scholar 

  24. Makrlík E, Hálová J, Kyrš M (1984) Collect Czech Chem Commun 49:39

    Google Scholar 

  25. Makrlík E, Vaňura P (1998) ACH Models Chem 135:213

    Google Scholar 

  26. Szigeti Z, Malon A, Vigassy T, Csokai V, Grün A, Wygladacz K, Ye N, Xu C, Chebny VJ, Bitter I, Rathore R, Bakker E, Pretsch E (2006) Anal Chim Acta 572:1

    Article  CAS  Google Scholar 

  27. Frisch MJ, Trucks GW, Schlegel HB, Scuseria GE, Robb MA, Cheeseman JR, Montgomery JA Jr, Vreven T, Kudin KN, Burant JC, Millam JM, Iyengar SS, Tomasi J, Barone V, Mennucci B, Cossi M, Scalmani G, Rega N, Petersson GA, Nakatsuji H, Hada M, Ehara M, Toyota K, Fukuda R, Hasegawa J, Ishida M, Nakajima T, Honda Y, Kitao O, Nakai H, Klene M, Li X, Knox JE, Hratchian HP, Cross JB, Bakken V, Adamo C, Jaramillo J, Gomperts R, Stratmann RE, Yazyev O, Austin AJ, Cammi R, Pomelli C, Ochterski JW, Ayala PY, Morokuma K, Voth GA, Salvador P, Dannenberg JJ, Zakrzewski VG, Dapprich S, Daniels AD, Strain MC, Farkas O, Malick DK, Rabuck AD, Raghavachari K, Foresman JB, Ortiz JV, Cui Q, Baboul AG, Clifford S, Cioslowski J, Stefanov BB, Liu G, Liashenko A, Piskorz P, Komaromi I, Martin RL, Fox DJ, Keith T, Al-Laham MA, Peng CY, Nanayakkara A, Challacombe M, Gill PMW, Johnson B, Chen W, Wong MW, Gonzalez C, Pople JA (2004) Gaussian 03, Revision C. 02. Gaussian Inc., Wallingford

    Google Scholar 

  28. Kříž J, Dybal J, Makrlík E, Vaňura P, Lang J (2007) Supramol Chem 19:419

    Article  Google Scholar 

  29. Kříž J, Dybal J, Makrlík E, Vaňura P (2008) Supramol Chem 20:387

    Article  Google Scholar 

  30. Kříž J, Dybal J, Makrlík E, Budka J, Vaňura P (2008) Supramol Chem 20:487

    Article  Google Scholar 

  31. Kříž J, Dybal J, Makrlík E, Budka J (2008) J Phys Chem A 112:10236

    Article  Google Scholar 

  32. Kříž J, Dybal J, Makrlík E, Budka J, Vaňura P (2009) J Phys Chem A 113:5896

    Article  Google Scholar 

Download references

Acknowledgments

This work was supported by the Czech Ministry of Education, Youth, and Sports projects MSM 4977751303, MSM 6046137301, and MSM 6046137307.

Author information

Authors and Affiliations

  1. Faculty of Applied Sciences, University of West Bohemia, Pilsen, Czech Republic

    Emanuel Makrlík

  2. Institute of Macromolecular Chemistry, Academy of Sciences of the Czech Republic, Prague, Czech Republic

    Jiří Dybal

  3. Institute of Chemical Technology, Prague, Czech Republic

    Jiřina Švorčíková, Jan Budka & Petr Vaňura

Authors
  1. Emanuel Makrlík
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Jiří Dybal
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Jiřina Švorčíková
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Jan Budka
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Petr Vaňura
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Emanuel Makrlík.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Makrlík, E., Dybal, J., Švorčíková, J. et al. Solvent extraction of silver trifluoromethanesulfonate from water into nitrobenzene in the presence of silver ionophore IV. Monatsh Chem 141, 507–510 (2010). https://doi.org/10.1007/s00706-010-0293-5

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s00706-010-0293-5

Keywords

Search

Navigation