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Pairwise energy effect of cyclic conjugation in benzo-annelated perylenes

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Abstract

Previous analysis of cyclic conjugation in benzo-annelated perylenes has revealed that annelation of a benzene ring in the angular position increases the extent of cyclic conjugation in the central ring whereas annelation of a benzene ring in the linear position reduces it. We now present a general method for assessing the effect of a ring on the energy effect of cyclic conjugation in another ring. The respective quantity, referred to as the pairwise energy effect, is used to rationalize specific modes of cyclic conjugation in benzo-annelated perylenes.

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Acknowledgments

S.R. and I.G. were supported by the Serbian Ministry of Science, through Grant no. 144015G. W.L. was supported by the Austrian Science Fund (FWF) (Project 19335-N17).

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Authors and Affiliations

  1. Faculty of Science, P.O. Box 60, 34000, Kragujevac, Serbia

    Ivan Gutman & Slavko Radenković

  2. Institute of Applied Synthetic Chemistry, Vienna University of Technology, Getreidemarkt 9/163-AC, 1060, Vienna, Austria

    Wolfgang Linert

Authors
  1. Ivan Gutman
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  2. Slavko Radenković
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  3. Wolfgang Linert
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Correspondence to Slavko Radenković.

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Gutman, I., Radenković, S. & Linert, W. Pairwise energy effect of cyclic conjugation in benzo-annelated perylenes. Monatsh Chem 141, 401–407 (2010). https://doi.org/10.1007/s00706-010-0270-z

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  • DOI: https://doi.org/10.1007/s00706-010-0270-z

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