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Catalytic hypervalent iodine oxidation of alcohols to corresponding aldehydes or ketones using 2,2,6,6-tetramethylpiperidinyl-1-oxy and potassium peroxodisulfate

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Abstract

An efficient, facile, and mild oxidation of alcohols to the corresponding aldehydes or ketones with potassium peroxodisulfate and 2,2,6,6-tetramethylpiperidinyl-1-oxy in the presence of a catalytic amount of iodobenzene is reported. The oxidation proceeded in a mixed solvent to afford carbonyl compounds in moderate to excellent yields. A possible mechanism for the oxidation is proposed.

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Acknowledgments

We are grateful to Nanjing University of Science and Technology for financial support.

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Authors and Affiliations

  1. School of Chemical Engineering, Nanjing University of Science and Technology, Nanjing, 210094, China

    Chenjie Zhu, Lei Ji & Yunyang Wei

Authors
  1. Chenjie Zhu
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  2. Lei Ji
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  3. Yunyang Wei
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Correspondence to Yunyang Wei.

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Zhu, C., Ji, L. & Wei, Y. Catalytic hypervalent iodine oxidation of alcohols to corresponding aldehydes or ketones using 2,2,6,6-tetramethylpiperidinyl-1-oxy and potassium peroxodisulfate. Monatsh Chem 141, 327–331 (2010). https://doi.org/10.1007/s00706-010-0260-1

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  • DOI: https://doi.org/10.1007/s00706-010-0260-1

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