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A combined experimental and theoretical study on the complexation of the ammonium ion with benzo-18-crown-6

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Abstract

From extraction experiments in the two-phase water/nitrobenzene system and γ-activity measurements, the stability constant of the benzo-18-crown-6–ammonium complex in nitrobenzene saturated with water was determined. Furthermore, the structure of the resulting complex was derived by means of theoretical calculations at the density functional level.

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Acknowledgments

This work was supported by the Czech Ministry of Education, Youth, and Sports, projects MSM 4977751303 and MSM 6046137307. The computer time at the MetaCentrum (project MSM 6383917201), as well as at the Institute of Physics (computer Luna/Apollo), Academy of Sciences of the Czech Republic, is gratefully acknowledged.

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Authors and Affiliations

  1. Institute of Macromolecular Chemistry, Academy of Sciences of the Czech Republic, Prague, Czech Republic

    Petr Toman

  2. Faculty of Applied Sciences, University of West Bohemia, Pilsen, Czech Republic

    Emanuel Makrlík

  3. Institute of Chemical Technology, Prague, Czech Republic

    Petr Vaňura

Authors
  1. Petr Toman
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  2. Emanuel Makrlík
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  3. Petr Vaňura
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Corresponding author

Correspondence to Emanuel Makrlík.

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Toman, P., Makrlík, E. & Vaňura, P. A combined experimental and theoretical study on the complexation of the ammonium ion with benzo-18-crown-6. Monatsh Chem 141, 301–304 (2010). https://doi.org/10.1007/s00706-010-0259-7

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  • DOI: https://doi.org/10.1007/s00706-010-0259-7

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