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Selective and efficient oxidation of sulfides to sulfoxides using ammonium cerium (IV) nitrate in the presence of a catalytic amount of KBr or NaBr

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Abstract

A wide range of aliphatic or aromatic sulfides are selectively oxidized to the corresponding sulfoxides using ammonium cerium (IV) nitrate (CAN) and a catalytic amount of KBr or NaBr in the presence of wet SiO2 in CH2Cl2 under heterogeneous conditions in moderate to high yields.

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Authors and Affiliations

  1. Faculty of Chemistry, Bu-Ali Sina University, Hamadan, Iran

    Mohammad Ali Zolfigol

  2. Department of Chemistry, Faculty of Science, University of Kurdistan, Sanandaj, Iran

    Kamal Amani & Maryam Hajjami

  3. Department of Chemistry, Faculty of Science, Ilam University, Ilam, Iran

    Arash Ghorbani-Choghamarani

Authors
  1. Mohammad Ali Zolfigol
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  2. Kamal Amani
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  3. Maryam Hajjami
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  4. Arash Ghorbani-Choghamarani
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Corresponding authors

Correspondence to Mohammad Ali Zolfigol or Kamal Amani.

Additional information

Correspondence: Mohammad Ali Zolfigol, Faculty of Chemistry, Bu-Ali Sina University, P.O. Box 6517838683, Hamadan, Iran; Kamal Amani, Department of Chemistry, Faculty of Science, University of Kurdistan, P.O. Box 6617715175, Sanandaj, Iran.

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Zolfigol, M., Amani, K., Hajjami, M. et al. Selective and efficient oxidation of sulfides to sulfoxides using ammonium cerium (IV) nitrate in the presence of a catalytic amount of KBr or NaBr. Monatsh Chem 139, 895–899 (2008). https://doi.org/10.1007/s00706-008-0868-6

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  • DOI: https://doi.org/10.1007/s00706-008-0868-6

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