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Synthesis, spectroscopic, and electrochemical properties of three tetrathiafulvalenes attached to perylene

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Abstract

Three donor–acceptor dyads 1–3 comprising of a tetrathiafulvalene (TTF) unit linked with perylene by a simple σ-bond were synthesized and characterized. Spectroscopy and cyclic voltammetry provided an indication that intramolecular charge-transfer interactions in their ground states between TTF and perylene for dyads 1–3 are negligible. Compared with the compound perylene, dyads 1–3 exhibited large fluorescence quenching, which might be ascribed to photo-induced electron transfer interaction between TTF and perylene units in the excited state.

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Authors and Affiliations

  1. Laboratory of Advanced Materials, Institute of Fine Chemicals, East China University of Science and Technology, Shanghai, P.R. China

    Haixiao Qiu, Chengyun Wang, Jinfeng Xu & Yongjia Shen

  2. Key Laboratory of Organosilicon Chemistry and Material Technology of Ministry of Education, Hangzhou Normal University, Hangzhou, China

    Guoqiao Lai

Authors
  1. Haixiao Qiu
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  2. Chengyun Wang
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  3. Jinfeng Xu
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  4. Guoqiao Lai
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  5. Yongjia Shen
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Corresponding author

Correspondence to Yongjia Shen.

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Correspondence: Yongjia Shen, Laboratory of Advanced Materials, Institute of Fine Chemicals, East China University of Science and Technology, Shanghai 200237, P.R. China.

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Qiu, H., Wang, C., Xu, J. et al. Synthesis, spectroscopic, and electrochemical properties of three tetrathiafulvalenes attached to perylene. Monatsh Chem 139, 1357–1362 (2008). https://doi.org/10.1007/s00706-008-0863-y

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  • DOI: https://doi.org/10.1007/s00706-008-0863-y

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