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Application of various ionic liquids as cosolvents for chloroperoxidase-catalysed biotransformations

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Abstract

Chloroperoxidase from Caldariomyces fumago catalyses oxidation of indole and thioanisole in reaction mixtures containing up to 40% (v/v) of different ionic liquids (ILs). Results indicate that ILs containing tosylate, trifluoroacetate, chloride, and methylsulfate anions are suitable cosolvents for these transformations, yielding high enantiomeric excess and good conversion rates.

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Authors and Affiliations

  1. Institute of Organic Chemistry, University of Vienna, Währingerstrasse 38, 1090, Vienna, Austria

    Roman J. Lichtenecker & Walther Schmid

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  1. Roman J. Lichtenecker
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  2. Walther Schmid
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Correspondence to Walther Schmid.

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Lichtenecker, R.J., Schmid, W. Application of various ionic liquids as cosolvents for chloroperoxidase-catalysed biotransformations. Monatsh Chem 140, 509–512 (2009). https://doi.org/10.1007/s00706-008-0081-7

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  • DOI: https://doi.org/10.1007/s00706-008-0081-7

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