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Facile synthesis of highly functionalized stable ketenimines by a three-component reaction of alkyl isocyanides, dialkyl acetylenedicarboxylates and ethyl carbazones

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Abstract

The reactive intermediate generated by the reaction of alkyl isocyanides and dialkyl acetylenedicarboxylates was trapped by ethyl carbazones to produce stable ketenimine derivatives in good yield. The reaction is characterized by mild conditions, high selectivity, and tolerance to various functional groups.

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Authors and Affiliations

  1. Department of Chemistry, Islamic Azad University, Yazd Branch, Yazd, Iran

    Mohammad Anary-Abbasinejad, Hossein Anaraki-Ardakani & Fatemeh Ghanea

Authors
  1. Mohammad Anary-Abbasinejad
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  2. Hossein Anaraki-Ardakani
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  3. Fatemeh Ghanea
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Correspondence to Mohammad Anary-Abbasinejad.

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Anary-Abbasinejad, M., Anaraki-Ardakani, H. & Ghanea, F. Facile synthesis of highly functionalized stable ketenimines by a three-component reaction of alkyl isocyanides, dialkyl acetylenedicarboxylates and ethyl carbazones. Monatsh Chem 140, 397–400 (2009). https://doi.org/10.1007/s00706-008-0039-9

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  • DOI: https://doi.org/10.1007/s00706-008-0039-9

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