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Inhibition of J-aggregation of meso-tetra(4-sulfonatophenyl)porphyrin by an ionic liquid with π-conjugated character

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Abstract

UV–visible spectral observations indicate that the J-aggregation of protonated meso-tetra(4-sulfonatophenyl)porphyrin ([H2TSPP]2+) under acidic conditions is completely inhibited by the π–π counteraction between 1-butyl-pyridinium tetrafluoroborate ([bpy]BF4) and [H2TSPP]2+. The studies also suggest that the intermolecular π–π force is of relative importance for the J-aggregates of [H2TSPP]2+ and the intermolecular electrostatic force for the H-aggregates.

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References

  1. Kano K, Fukuda K, Wakami H, Nishiyabu R, Pasternack RF (2000) J Am Chem Soc 122:7494

    Article  CAS  Google Scholar 

  2. Kano K, Kobayashi T (2001) J Chem Phys 116:184

    Article  CAS  Google Scholar 

  3. Andrade SM, Teixeira R, Costa SMB, Sobral AJFN (2008) Biophys Chem 133:1

    Article  CAS  Google Scholar 

  4. Rahman M, Harmon HJ (2007) J Porp Phthal 11:125

    Article  CAS  Google Scholar 

  5. Higgins DA, Barbara PF (1995) J Phys Chem 99:3

    Article  CAS  Google Scholar 

  6. Akins DL, Zhu HR, Guo C (1996) J Phys Chem 100:5420

    Article  CAS  Google Scholar 

  7. Akins DL, Zhu HR, Guo C (1994) J Phys Chem 98:3612

    Article  CAS  Google Scholar 

  8. Choi MY, Pollard JA, Webb MA, McHale JL (2003) J Am Chem Soc 125:810

    Article  CAS  Google Scholar 

  9. Yildirim H, Iseri EI, Gülen D (2004) Chem Phys Lett 391:302

    Article  CAS  Google Scholar 

  10. Egawa Y, Hayashida R, Anzai J (2007) Langmuir 23:13146

    Article  CAS  Google Scholar 

  11. Wu J-J, Ma HL, Mao H-S, Wang Y, Jin W-J (2005) J Photochem Photobiol B 173:296

    Article  CAS  Google Scholar 

  12. Ohno O, Kaizu Y, Kobayashi H (1993) J Chem Phys 99:4128

    Article  CAS  Google Scholar 

  13. Ribó JM, Crusats J, Farrera J-A, Valero ML (1994) Chem Commun 6:681

    Google Scholar 

  14. Rubires R, Crusats J, El-Hachemi Z, Jaramillo T, López M, Valls E, Farrera J-A, Ribó JM (1999) New J Chem 23:189

    Article  CAS  Google Scholar 

  15. Maiti NC, Mazumdar S, Periasamy N (1998) J Phys Chem B 102:1528

    Article  CAS  Google Scholar 

  16. Maiti NC, Ravikanth M, Mazumdar S, Periasamy N (1995) J Phys Chem 99:17192

    Article  CAS  Google Scholar 

  17. Sutter TPG, Rahimi R, Hambright P, Bommer JC, Kumar M, Neta P (1993) J Chem Soc Faraday Trans 89:495

    Article  CAS  Google Scholar 

  18. Behar D, Neta P, Carl S (2002) J Phys Chem A 106:3139

    Article  CAS  Google Scholar 

Download references

Acknowledgments

The National Natural Science Foundation of China (nos. 20673039, 20533010, 20590366) and the Science and Technology Commission of Shanghai Municipality (06JC14023, 06SR07101) are gratefully acknowledged for financial support.

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Authors and Affiliations

  1. Shanghai Key Laboratory of Green Chemistry and Chemical Processes, Department of Chemistry, East China Normal University, Shanghai, 200062, China

    Qing-Xia Wan, Ye Liu & Sa-Sa Wang

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  1. Qing-Xia Wan
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  2. Ye Liu
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  3. Sa-Sa Wang
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Correspondence to Ye Liu.

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Wan, QX., Liu, Y. & Wang, SS. Inhibition of J-aggregation of meso-tetra(4-sulfonatophenyl)porphyrin by an ionic liquid with π-conjugated character. Monatsh Chem 140, 335–337 (2009). https://doi.org/10.1007/s00706-008-0028-z

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  • DOI: https://doi.org/10.1007/s00706-008-0028-z

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