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Determination of extractable chromium from leather

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Abstract

People are exposed to chromium ions from leather materials due to everyday contact with different textile objects. The problem is that Cr(VI) is extremely toxic and may cause contact allergic dermatitis on the skin and may also be a trigger for many diseases. Huge amounts of chromium ions are released by waste waters to rivers after chromium-tanning processes in the leather industry; the presence of chromium is not only a problem for human health, but also for the environment. For this reason it is extremely important to monitor the presence of chromium as Cr(VI) and as total chromium. This study aims to present an appropriate analytical method for monitoring Cr(VI) and the total chromium present on leather materials. Applying this method to chromium-tanned leather samples, it was observed that the amounts of total chromium as well as of Cr(VI) are higher than prescribed and recommended by different regulations. Chromium(VI) exceeded the limit of 3 mg/kg in the majority of tested materials, while the total chromium exceeded the limit of 50 mg/kg in all tested samples. For this reason, it is recommended to avoid direct and prolonged contact of those materials with the skin.

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References

  1. Sundar VJ, Rao JR, Muralidharan C (2002) J Cleaner Prod 10:69

    Article  Google Scholar 

  2. Sreeram KJ, Ramasami T (2003) Resour Conserv Recycling 38:185

    Article  Google Scholar 

  3. Barnhart J (1997) Regul Toxicol Pharmacol 26:S3

    Article  CAS  Google Scholar 

  4. Lierde VV, Chéry CC, Moens L, Vanhaecke F (2005) Electrophoresis 26:1703

    Article  Google Scholar 

  5. Mignini F, Streccioni V, Baldo M, Vitali M, Indraccolo U, Bernacchia G, Cocchioni M (2004) Prev Med 39:767

    Article  CAS  Google Scholar 

  6. Babu NKC, Asma K, Raghupathi A, Venba R, Rames R, Sadulla S (1995) J Cleaner Prod 13:1189

    Google Scholar 

  7. Srivastava S, Thakur IS (2006) Bioresou Technol 97:1167

    Article  CAS  Google Scholar 

  8. Hafez A, El-Manharawy S (2004) Desalination 165:141

    CAS  Google Scholar 

  9. Alvarez-Bernal D, Contreras-Ramos SM, Trujillo-Tapia N, Olalde-Portugal V, Frías-Hernández JT, Dendooven L (2006) Appl Soil Ecol 33:269

    Article  Google Scholar 

  10. Meriç S, De Nicola E, Iaccarino M, Gallo M, Di Gennaro A, Morrone G, Warnau M, Belgiorno V, Pagano G (2005) Chemosphere 61:208

    Article  Google Scholar 

  11. Mu C, Lin W, Zhang M, Zhu Q (2003) Waste Manag 23:835

    Article  CAS  Google Scholar 

  12. Lyubchik SIK, Lyubchik AI, Galushko OL, Tikhonova LP, Vital J, Fonseca IM, Lyubchik SB (2004) Colloids Surf A Physicochem. Eng Aspects 242:151

    Article  CAS  Google Scholar 

  13. Monteiro MIC, Fraga ICS, Yallouz AV, de Oliveira NMM, Ribeiro SH (2002) Talanta 58:629

    Article  CAS  Google Scholar 

  14. Cespón-Romer RM, Yebra-Biurrun MC, Bermejo-Barrera MP (1996) Analytica Chimica Acta 327:37

    Article  Google Scholar 

  15. Sperling M, Xu S, Welz B (1992) Anal Chem 64:3101

    Article  CAS  Google Scholar 

  16. Walsh AR, O′Halloran J (1996) Water Res 30:2392

    Google Scholar 

  17. Posta J, Alimonti A, Petrucci F, Caroli S (1996) Analytica Chimica Acta 325:185

    Article  CAS  Google Scholar 

  18. Balasubramanian S, Pugalenthi V (1999) Talanta 50:457

    Article  CAS  Google Scholar 

  19. Hess Natur quality guidelines leather version 2.0

  20. Zeiner M, Rezic I, Steffan I (2006) Toxicol Lett 164:S187

    Article  Google Scholar 

Download references

Acknowledgments

We are grateful to Prof. I. Steffan for discussions and to the OeAD for financial support.

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Authors and Affiliations

  1. Laboratory of Analytical Chemistry, Department of Applied Chemistry, Faculty of Textile Technology, University of Zagreb, Prilaz Baruna Filipovića 28a, 10000, Zagreb, Croatia

    Iva Rezić

  2. Faculty of Chemistry, Department of Chemistry, University of Vienna, Vienna, Austria

    Michaela Zeiner

Authors
  1. Iva Rezić
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  2. Michaela Zeiner
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Correspondence to Iva Rezić.

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Rezić, I., Zeiner, M. Determination of extractable chromium from leather. Monatsh Chem 140, 325–328 (2009). https://doi.org/10.1007/s00706-008-0026-1

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  • DOI: https://doi.org/10.1007/s00706-008-0026-1

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